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Salen 型铝和锌配合物作为双面 Janus 化合物:在分子传感和聚合催化中的贡献。

Salen-type aluminum and zinc complexes as two-faced Janus compounds: contribution to molecular sensing and polymerization catalysis.

机构信息

Dipartimento di Chimica e Biologia "Adolfo Zambelli", Università degli Studi di Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, SA, Italy.

出版信息

Dalton Trans. 2020 Dec 8;49(46):16533-16550. doi: 10.1039/d0dt02639e.

DOI:10.1039/d0dt02639e
PMID:33140763
Abstract

The aim of the present review is to highlight the most recent achievements in different fields of application of salen-based zinc and aluminum complexes. More specifically this article focuses on the use of aluminum and zinc salen-type complexes as optical probes for biologically relevant molecules, as catalysts for the ring opening polymerization (ROP) of cyclic esters and co-polymerization of epoxides and anhydrides (ROCOP) and in the chemical fixation of carbon dioxide (CO2). The intention is to provide an overview of the most recent results from our group within the framework of the state-of-art-results in the literature.

摘要

本次综述的目的在于强调基于席夫碱的锌和铝配合物在不同应用领域的最新成果。具体而言,本文主要关注铝和锌席夫碱配合物作为生物相关分子的光学探针、环状酯开环聚合(ROP)和环氧化物与酸酐共聚(ROCOP)以及二氧化碳(CO2)化学固定的催化剂。本文旨在根据文献中的最新技术成果,概述我们小组的最新研究成果。

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