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手性对单壁碳纳米管中电子输运的影响。

Chirality effects on an electron transport in single-walled carbon nanotube.

作者信息

Charoenpakdee J, Suntijitrungruang Ongart, Boonchui S

机构信息

Department of Physics, Faculty of Science, Kasetsart University, Bangkok, 10900, Thailand.

Center of Rubber and Polymer Materials in Agriculture and Industry (RPM), Faculty of Science, Kasetsart University, Bangkok, 10900, Thailand.

出版信息

Sci Rep. 2020 Nov 3;10(1):18949. doi: 10.1038/s41598-020-76047-9.

Abstract

In our work, we investigate characteristics of conductivity for single-walled carbon nanotubes caused by spin-orbit interaction. In the case study of chirality indexes, we especially research on the three types of single-walled carbon nanotubes which are the zigzag, the chiral, and the armchair. The mathematical analysis employed for our works is the Green-Kubo Method. For the theoretical results of our work, we discover that the chirality of single-walled carbon nanotubes impacts the interaction leading to the spin polarization of conductivity. We acknowledge such asymmetry characteristics by calculating the longitudinal current-current correlation function difference between a positive and negative wave vector in which there is the typical chiral-dependent. We also find out that the temperature and the frequency of electrons affect the function producing the different characteristics of the conductivity. From particular simulations, we obtain that the correlation decrease when the temperature increase for a low frequency of electrons. For high frequency, the correlation is nonmonotonic temperature dependence. The results of the phenomena investigated from our study express different degrees of spin polarization in each chiral of single-walled carbon nanotube and significant effects on temperature-dependent charge transport according to carrier backscattering. By chiral-induced spin selectivity that produces different spin polarization, our work could be applied for intriguing optimization charge transport.

摘要

在我们的工作中,我们研究了由自旋轨道相互作用引起的单壁碳纳米管的电导率特性。在对手性指数的案例研究中,我们特别研究了锯齿形、手性和扶手椅形这三种类型的单壁碳纳米管。我们工作中采用的数学分析方法是格林 - 库博方法。对于我们工作的理论结果,我们发现单壁碳纳米管的手性会影响相互作用,从而导致电导率的自旋极化。我们通过计算具有典型手性依赖性的正负波矢之间的纵向电流 - 电流关联函数差来确认这种不对称特性。我们还发现电子的温度和频率会影响产生不同电导率特性的函数。从特定的模拟中,我们得出对于低频电子,温度升高时关联会降低。对于高频,关联具有非单调的温度依赖性。我们研究中所研究现象的结果表明,单壁碳纳米管的每种手性都存在不同程度的自旋极化,并且根据载流子背散射对温度依赖的电荷传输有显著影响。通过产生不同自旋极化的手性诱导自旋选择性,我们的工作可用于有趣的优化电荷传输。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10f2/7641154/89226bfd8b4c/41598_2020_76047_Fig1_HTML.jpg

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