Removal and transformation of unconventional air pollutants in flue gas in the cement kiln-end facilities.

To understand the removal and transformation behaviors of unconventional air pollutants (polycyclic aromatic hydrocarbons, heavy metals and carbonyl compounds) in the flue gas in cement kiln-end facilities, including SP boiler, a slide stream SCR-DeNO system, raw mill and baghouse filter, the gas and particle matter samples at the inlets and outlets of each kiln-end installation were collected and the contents of the unconventional air pollutants were measured. The results showed that the concentrations of the polycyclic aromatic hydrocarbons (PAHs) in particulate and gas-phase, heavy metals in the particulate matter were 17.5 μg m, 48.7 μg m and 3113.1 μg m at the inlet of the SP boiler, and decreased to 0.6 μg m, 17.7 μg m and 39.7 μg m, respectively, while the concentrations of carbonyl compounds in gas-phase increased from 1988.5 μg m to 2844.5 μg m after flue gas successively passed through the kiln-end facilities. The cooling of flue gas and the precipitation of coarse particulate matter in the SP boiler resulted in a significant decrease of PAHs concentration in both gas-phase and particulate-phase, as well as the heavy metal concentration in the particulate-phase, while the SP boiler hardly had any influence on the removal and transformation of carbonyl compounds. Grinding and heat exchange in the raw mill accelerated the volatilization of compounds with the low boiling point in the raw meal, which increased concentrations of gas-phase PAHs and carbonyl compounds. When flue gas passed through the baghouse filter, almost all particulate-phase PAHs, heavy metals and most of the gas-phase PAHs, were removed while the carbonyl compounds concentration maintained unchanged. Furthermore, some portion of gas-phase PAHs and carbonyl compounds were removed by the SCR-DeNO system.