Rider Marie S, Sokolikova Maria, Hanham Stephen M, Navarro-Cía Miguel, Haynes Peter D, Lee Derek K K, Daniele Maddalena, Cestelli Guidi Mariangela, Mattevi Cecilia, Lupi Stefano, Giannini Vincenzo
The Blackett Laboratory, Imperial College London, London SW7 2AZ, UK.
Nanoscale. 2020 Nov 28;12(44):22817-22825. doi: 10.1039/d0nr06523d. Epub 2020 Nov 11.
Topological insulator nanoparticles (TINPs) host topologically protected Dirac surface states, just like their bulk counterparts. For TINPs of radius <100 nm, quantum confinement on the surface results in the discretization of the Dirac cone. This system of discrete energy levels is referred to as a topological quantum dot (TQD) with energy level spacing on the order of Terahertz (THz), which is tunable with material-type and particle size. The presence of these discretized energy levels in turn leads to a new electron-mediated phonon-light coupling in the THz range, and the resulting mode can be observed in the absorption cross-section of the TINPs. We present the first experimental evidence of this new quantum phenomenon in BiTe topological quantum dots, remarkably observed at room temperature.
拓扑绝缘体纳米颗粒(TINPs)与它们的块体材料一样,拥有拓扑保护的狄拉克表面态。对于半径小于100纳米的TINPs,表面的量子限制导致狄拉克锥离散化。这种离散能级系统被称为拓扑量子点(TQD),其能级间距在太赫兹(THz)量级,可通过材料类型和颗粒尺寸进行调节。这些离散能级的存在反过来会在太赫兹范围内导致一种新的电子介导的声子 - 光耦合,并且可以在TINPs的吸收截面中观察到由此产生的模式。我们首次在BiTe拓扑量子点中给出了这种新量子现象的实验证据,该现象在室温下就能显著观察到。