Chemistry and Materials Science Program, Lakehead University, 955 Oliver Road, Thunder Bay, ON, P7B 5E1, Canada.
Physics Department, Lakehead University, 955 Oliver Road, Thunder Bay, ON, P7B 5E1, Canada.
Sci Rep. 2020 Nov 18;10(1):20117. doi: 10.1038/s41598-020-77050-w.
Polycrystalline Lead Oxide (poly-PbO) was considered one of the most promising photoconductors for the direct conversion X-ray medical imaging detectors due to its previous success in optical imaging, i.e., as an optical target in so-called Plumbicon video pick-up tubes. However, a signal lag which accompanies X-ray excitation, makes poly-PbO inapplicable as an X-ray-to-charge transducer in real-time X-ray imaging. In contrast, the recently synthesized Amorphous Lead Oxide (a-PbO) photoconductor is essentially lag-free. Here, we report on our approach to a PbO detector where a thin layer of a-PbO is combined with a thick layer of poly-PbO for lag-free operation. In the presented a-PbO/poly-PbO bilayer structure, the poly-PbO layer serves as an X-ray-to-charge transducer while the a-PbO acts as a lag prevention layer. The hole mobility in the a-PbO/poly-PbO bilayer structure was measured by photo-Charge Extraction by Linearly Increasing Voltage technique at different temperatures and electric fields to investigate charge transport properties. It was found that the hole mobility is similar to that in a-Se-currently the only commercially viable photoconductor for the direct conversion X-ray detectors. Evaluation of the X-ray temporal performance demonstrated complete suppression of signal lag, allowing operation of the a-PbO/poly-PbO detector in real-time imaging.
多晶氧化铅(poly-PbO)被认为是最有前途的直接转换 X 射线医学成像探测器光电导体制备材料之一,因为它在光学成像方面取得了成功,即作为所谓的 Plumbicon 视频摄像管中的光学靶材。然而,由于 X 射线激发带来的信号滞后,使得 poly-PbO 不适用于实时 X 射线成像中的 X 射线-电荷转换器。相比之下,最近合成的非晶态氧化铅(a-PbO)光电导体制备材料本质上没有滞后。在这里,我们报告了一种 PbO 探测器的方法,其中薄的 a-PbO 层与厚的 poly-PbO 层结合,以实现无滞后操作。在提出的 a-PbO/poly-PbO 双层结构中,poly-PbO 层作为 X 射线-电荷转换器,而 a-PbO 层作为防止滞后的层。通过线性增加电压技术的光电荷提取测量了不同温度和电场下 a-PbO/poly-PbO 双层结构中的空穴迁移率,以研究电荷输运特性。结果表明,空穴迁移率与目前唯一商业上可行的直接转换 X 射线探测器的 a-Se 相似。X 射线时间性能的评估表明完全抑制了信号滞后,使得 a-PbO/poly-PbO 探测器能够实时成像。