Grynko Oleksandr, Thibault Tristen, Pineau Emma, Reznik Alla
Chemistry and Materials Science Program, Lakehead University, Thunder Bay, ON P7B 5E1, Canada.
Physics Department, Lakehead University, Thunder Bay, ON P7B 5E1, Canada.
Sensors (Basel). 2021 Nov 3;21(21):7321. doi: 10.3390/s21217321.
The photoconductor layer is an important component of direct conversion flat panel X-ray imagers (FPXI); thus, it should be carefully selected to meet the requirements for the X-ray imaging detector, and its properties should be clearly understood to develop the most optimal detector design. Currently, amorphous selenium (a-Se) is the only photoconductor utilized in commercial direct conversion FPXIs for low-energy mammographic imaging, but it is not practically feasible for higher-energy diagnostic imaging. Amorphous lead oxide (a-PbO) photoconductor is considered as a replacement to a-Se in radiography, fluoroscopy, and tomosynthesis applications. In this work, we investigated the X-ray sensitivity of a-PbO, one of the most important parameters for X-ray photoconductors, and examined the underlying mechanisms responsible for charge generation and recombination. The X-ray sensitivity in terms of electron-hole pair creation energy, , was measured in a range of electric fields, X-ray energies, and exposure levels. decreases with the electric field and X-ray energy, saturating at 18-31 eV/ehp, depending on the energy of X-rays, but increases with the exposure rate. The peculiar dependencies of on these parameters lead to a conclusion that, at electric fields relevant to detector operation (~10 V/μm), the columnar recombination and the bulk recombination mechanisms interplay in the a-PbO photoconductor.
光电导体层是直接转换平板X射线成像器(FPXI)的重要组成部分;因此,应仔细选择以满足X射线成像探测器的要求,并且应清楚了解其特性,以开发出最优化的探测器设计。目前,非晶硒(a-Se)是商业直接转换FPXI中用于低能乳腺成像的唯一光电导体,但对于高能诊断成像来说,它在实际应用中并不可行。非晶氧化铅(a-PbO)光电导体被认为是在射线照相、荧光透视和断层合成应用中替代a-Se的材料。在这项工作中,我们研究了a-PbO的X射线灵敏度,这是X射线光电导体最重要的参数之一,并研究了负责电荷产生和复合的潜在机制。在一系列电场、X射线能量和曝光水平下,测量了以电子-空穴对产生能量表示的X射线灵敏度。随着电场和X射线能量的增加而降低,根据X射线的能量,在18-31 eV/ehp时达到饱和,但随着曝光率的增加而增加。对这些参数的特殊依赖性得出一个结论,即在与探测器操作相关的电场(~10 V/μm)下,柱状复合和体复合机制在a-PbO光电导体中相互作用。