基于噁唑（并）基取代的激发态分子内质子转移（ESIPT）的发射颜色可调的荧光团。
Emission color-tunable oxazol(in)yl-substituted excited-state intramolecular proton transfer (ESIPT)-based luminophores.
机构信息
Institute for Organic and Analytical Chemistry, University of Bremen, Leobener Straße NW2, D-28359 Bremen, Germany.
Leibniz University Hannover, Institute of Physical Chemistry and Electrochemistry, Callinstraße 3a, D-30167 Hannover, Germany.
出版信息
Chem Commun (Camb). 2020 Dec 21;56(98):15430-15433. doi: 10.1039/d0cc05780k. Epub 2020 Nov 24.
Abstract
Oxazolinyl- and arylchalcogenazolyl-substituted hydroxyfluorenes exhibiting excited-state intramolecular proton transfer (ESIPT) are described as potent and highly modular luminophores. Emission color tuning was achieved by varying the π-expansion and the insertion of different chalcogen atoms.
摘要
含有恶唑啉基和芳基硫代杂环唑基的羟基芴，表现出激发态分子内质子转移（ESIPT），是一种有效的、高度模块化的发光团。通过改变π扩展和插入不同的硫属原子，可以实现发射颜色的调谐。
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