He Chuan, Xiao Qingyi, Gong Fangyuan, Yang Yun, Ren Xipeng
School of Civil and Transportation Engineering, Hebei University of Technology, Tianjin 300401, China.
Administration Office, Tianjin Yongyang Highway Engineering Group Co., Ltd., Tianjin 301700, China.
Materials (Basel). 2020 Nov 21;13(22):5267. doi: 10.3390/ma13225267.
Due to its ability to degrade nitrogen oxides under ultraviolet, titanium dioxide has been applied in asphalt concrete to degrade automobile exhaust in recent years. To highlight the protection of road traffic environmental quality and mitigate automobile exhaust on human health, this study proposes combining titanium dioxide and active carbon into Sand-fog seal to form a pavement coating material with a photocatalytic function. It uses active carbon to reinforce the material's function, and the coupling agent for modification makes it well dispersed in the Sand-fog seal. The indoor experiments were carried out at 30 °C and relative humidity of 30%. It tested the composite material's degradation efficiency on nitrogen dioxide in relation to component proportions, coupling agents, and dosages. The study concluded that the optimal photocatalytic efficiency could be achieved when the ratio of active carbon to titanium dioxide is 0.6. After being modified by the titanate coupling agent and through Scanning Electron Microscope tests, it can be seen that materials can be well dispersed into the Sand-fog seal. When the composite material accounts for 10% of the fog seal, it can achieve the optimal photocatalytic efficiency of about 23.9%. The British pendulum tests show it has good skid resistance performance. Half a kilometer of concrete roadway was sprayed with the material coating in Tianjin, China. The photocatalytic experimental road degrades nitrogen oxides better than the original road. The method is feasible for practical implementation.
由于二氧化钛在紫外线照射下具有降解氮氧化物的能力,近年来已被应用于沥青混凝土中以降解汽车尾气。为突出对道路交通环境质量的保护并减轻汽车尾气对人体健康的影响,本研究提出将二氧化钛与活性炭结合到砂雾封层中,形成一种具有光催化功能的路面涂层材料。利用活性炭增强材料功能,通过偶联剂改性使其在砂雾封层中良好分散。室内实验在30℃、相对湿度30%的条件下进行。测试了复合材料对二氧化氮的降解效率与组分比例、偶联剂及用量的关系。研究得出,当活性炭与二氧化钛的比例为0.6时可实现最佳光催化效率。经钛酸酯偶联剂改性并通过扫描电子显微镜测试可知,材料能很好地分散到砂雾封层中。当复合材料占雾封层的10%时,可实现约23.9%的最佳光催化效率。英国摆式试验表明其具有良好的防滑性能。在中国天津,对半公里的混凝土路面喷洒了该材料涂层。光催化试验路段对氮氧化物的降解效果优于原路面。该方法实际实施可行。