Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 106, Taiwan, ROC.
Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 106, Taiwan, ROC; Research and Development Center for Smart Textile Technology, National Taipei University of Technology, Taipei 106, Taiwan, ROC; Department of Materials, Imperial College London, London SW7 2AZ, United Kingdom.
J Hazard Mater. 2021 May 15;410:124542. doi: 10.1016/j.jhazmat.2020.124542. Epub 2020 Nov 11.
A facile technique has been used to synthesize the strontium phosphate interlinked with graphitic carbon nitride nanosheets (SrP/g-CN NSs) nanocomposite for highly selective detection of acetaminophen (AP). The formation of SrP/g-CN NSs nanocomposite is evidenced by several spectroscopic and analytical methods. It was demonstrated that the SrP/g-CN NSs modified screen-printed carbon electrode (SPCE) exhibits excellent catalytic performance with low peak potential towards AP detection than those of pristine SrP-, g-CN NSs-, and bare- SPCEs. The outstanding electrochemical performance can be attributed to the robust synergistic effect between SrP and g-CN NSs. Likewise, g-CN NSs possess a porous multilayer network, which provides a large surface area, fast charge transferability, electrical conductivity, and numerous active sites. Under the optimal conditions, the fabricated sensor could detect AP with a linear relationship range from 0.01 to 370 µM, and the detection limit is calculated to be as low as 2.0 nM. The proposed sensor is successfully used to determine AP in water samples with satisfactory results.
一种简便的技术被用于合成与石墨相氮化碳纳米片交联的磷酸锶纳米复合材料(SrP/g-CN NSs),用于高度选择性检测对乙酰氨基酚(AP)。SrP/g-CN NSs 纳米复合材料的形成通过多种光谱和分析方法得到证实。结果表明,SrP/g-CN NSs 修饰的丝网印刷碳电极(SPCE)对 AP 的检测具有出色的催化性能,其峰电位比原始 SrP、g-CN NSs 和裸 SPCE 都要低。这种出色的电化学性能可归因于 SrP 和 g-CN NSs 之间的强大协同效应。同样,g-CN NSs 具有多孔多层网络,提供了较大的表面积、快速的电荷转移能力、导电性和众多的活性位点。在最佳条件下,所制备的传感器可以在 0.01 至 370 µM 的线性范围内检测 AP,检测限低至 2.0 nM。该传感器成功用于水样中 AP 的测定,结果令人满意。