Development of Eco-Sustainable PBAT-Based Blown Films and Performance Analysis for Food Packaging Applications.

In this work, eco-sustainable blown films with improved performance, suitable for flexible packaging applications requiring high ductility, were developed and characterized. Films were made by blending two bioplastics with complementary properties-the ductile and flexible poly(butylene-adipate--terephthalate) (PBAT) and the rigid and brittle poly(lactic acid) (PLA)-at a 60/40 mass ratio. With the aim of improving the blends' performance, the effects of two types of PLA, differing for viscosity and stereoregularity, and the addition of a commercial polymer chain extender (Joncryl), were analyzed. The use of the PLA with a viscosity ratio closer to PBAT and lower stereoregularity led to a finer morphology and better interfacial adhesion between the phases, and the addition of the chain extender further reduced the size of the dispersed phase domains, with beneficial effects on the mechanical response of the produced films. The best system composition, made by the blend of PBAT, amorphous PLA, and the compatibilizer, proved to have improved mechanical properties, with a good balance between stiffness and ductility and also good transparency and sealability, which are desirable features for flexible packaging applications.