AIE-based fluorescent sensors for low concentration toxic ion detection in water.

Ions, including anions and heavy metals, are extremely toxic and easily accumulate in the human body, threatening the health of humans and even causing human death at low concentrations. It is therefore necessary to detect these toxic ions in low concentrations in water. Fluorescent sensing is a good method for detecting these ions, but some conventional dyes often exhibit an aggregation caused quench (ACQ) effect in their solid state, limiting their large-scale application. Fluorescent probes based on aggregation-induced emission (AIE) properties have received significant attention due to their high fluorescence quantum yields in their nano aggragated states, easy fabrication, use of moderate conditions, and selevtive recognization of organic/inorganic compounds in water with obvious changes in fluorescence. We surmarize the recent advances of AIE-based sensors for low concentration toxic ion detection in water. The detection probes can be divided into three categories: chemical reaction types, chemical interaction types and physical interaction types. Chemical reaction types utilize nucleophilic addition and coordination reaction, while chemical interaction types rely on hydrogen bonding and anion-π interactions. The physical interaction types are composed of electrostatic attractions. We finally comment on the challenges and outlook of AIE-active sensors.