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概率、熵与吉布斯佯谬

Probability, Entropy, and Gibbs' Paradox(es).

作者信息

Swendsen Robert H

机构信息

Physics Department, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

出版信息

Entropy (Basel). 2018 Jun 9;20(6):450. doi: 10.3390/e20060450.

Abstract

Two distinct puzzles, which are both known as Gibbs' paradox, have interested physicists since they were first identified in the 1870s. They each have significance for the foundations of statistical mechanics and have led to lively discussions with a wide variety of suggested resolutions. Most proposed resolutions had involved quantum mechanics, although the original puzzles were entirely classical and were posed before quantum mechanics was invented. In this paper, I show that contrary to what has often been suggested, quantum mechanics is not essential for resolving the paradoxes. I present a resolution of the paradoxes that does not depend on quantum mechanics and includes the case of colloidal solutions, for which quantum mechanics is not relevant.

摘要

自19世纪70年代首次被发现以来,有两个截然不同但都被称为吉布斯悖论的谜题引起了物理学家的兴趣。它们各自对统计力学的基础具有重要意义,并引发了关于各种建议解决方案的热烈讨论。尽管最初的谜题完全是经典的,且是在量子力学发明之前提出的,但大多数提出的解决方案都涉及量子力学。在本文中,我表明,与通常的观点相反,量子力学对于解决这些悖论并非必不可少。我提出了一种不依赖于量子力学的悖论解决方案,其中包括量子力学不相关的胶体溶液的情况。

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