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吉布斯佯谬

The Gibbs Paradox.

作者信息

Saunders Simon

机构信息

Faculty of Philosophy, University of Oxford, Oxford OX2 6GG, UK.

出版信息

Entropy (Basel). 2018 Jul 25;20(8):552. doi: 10.3390/e20080552.

Abstract

The Gibbs Paradox is essentially a set of open questions as to how sameness of gases or fluids (or masses, more generally) are to be treated in thermodynamics and statistical mechanics. They have a variety of answers, some restricted to quantum theory (there is no classical solution), some to classical theory (the quantum case is different). The solution offered here applies to both in equal measure, and is based on the concept of particle indistinguishability (in the classical case, Gibbs' notion of 'generic phase'). Correctly understood, it is the elimination of sequence position as a labelling device, where sequences enter at the level of the tensor (or Cartesian) product of one-particle state spaces. In both cases it amounts to passing to the quotient space under permutations. 'Distinguishability', in the sense in which it is usually used in classical statistical mechanics, is a mathematically convenient, but physically muddled, fiction.

摘要

吉布斯佯谬本质上是一组关于在热力学和统计力学中如何处理气体或流体(或更一般地说,物质)的相同性的开放性问题。它们有各种各样的答案,有些局限于量子理论(不存在经典解),有些局限于经典理论(量子情况不同)。这里给出的解决方案在同等程度上适用于两者,并且基于粒子不可区分性的概念(在经典情况下,是吉布斯的“一般相”概念)。正确理解的话,它是消除序列位置作为一种标记手段,其中序列在单粒子态空间的张量(或笛卡尔)积层面出现。在这两种情况下,这都相当于在置换下过渡到商空间。在经典统计力学中通常使用的“可区分性”意义上,它是一种数学上方便但物理上混乱的虚构概念。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1289/7513078/b5359dc6f233/entropy-20-00552-g001.jpg

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