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基于镁离子传导生物聚合物复合膜电解质的固态双电层电容器：阻抗、电路建模、介电性能和电化学特性

Solid-State EDLC Device Based on Magnesium Ion-Conducting Biopolymer Composite Membrane Electrolytes: Impedance, Circuit Modeling, Dielectric Properties and Electrochemical Characteristics.

作者信息

Asnawi Ahmad S F M, Aziz Shujahadeen B, Saeed Salah R, Yusof Yuhanees M, Abdulwahid Rebar T, Al-Zangana Shakhawan, Karim Wrya O, Kadir Mohd F Z

机构信息

Chemical Engineering Section, Universiti Kuala Lumpur Malaysian Institute of Chemical & Bioengineering Technology (UniKL MICET), Alor Gajah 78000, Malacca, Malaysia.

Hameed majid Advanced Polymeric Materials Research Lab., Department of Physics, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani 46001, Iraq.

出版信息

Membranes (Basel). 2020 Dec 2;10(12):389. doi: 10.3390/membranes10120389.

DOI:10.3390/membranes10120389
PMID:33276495
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7760615/
Abstract

The polymer electrolyte based on Dx:Cs:Mg(CHCOO):Ni with three different glycerol concentrations have been prepared. The impedance study has verified that the electrolyte with 42 wt.% of glycerol (A3) has the highest ionic conductivity of 7.71 × 10 S cm at room temperature. The ionic conductivity is found to be influenced by the transport parameters. From the dielectric analysis, it was shown that the electrolytes in this system obeyed the non-Debye behavior. The A3 electrolyte exhibited a dominancy of ions ( > ) with a breakdown voltage of 2.08 V. The fabricated electrochemical double layer capacitor (EDLC) achieved the specific capacitance values of 24.46 F/g and 39.68 F/g via the cyclic voltammetry (CV) curve and the charge-discharge profile, respectively. The other significant parameters to evaluate the performance of EDLC have been determined, such as internal resistance (186.80 to 202.27 Ω) energy density (4.46 Wh/kg), power density (500.58 to 558.57 W/kg) and efficiency (92.88%).

摘要

制备了基于Dx:Cs:Mg(CHCOO):Ni且含有三种不同甘油浓度的聚合物电解质。阻抗研究证实，甘油含量为42 wt.%的电解质（A3）在室温下具有最高的离子电导率，为7.71×10 S/cm。发现离子电导率受传输参数影响。通过介电分析表明，该体系中的电解质符合非德拜行为。A3电解质表现出离子优势（>），击穿电压为2.08 V。所制备的电化学双层电容器（EDLC）通过循环伏安法（CV）曲线和充放电曲线分别实现了24.46 F/g和39.68 F/g的比电容值。还确定了评估EDLC性能的其他重要参数，如内阻（186.80至202.27Ω）、能量密度（4.46 Wh/kg）、功率密度（500.58至558.57 W/kg）和效率（92.88%）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a1c/7760615/94dd75eab90a/membranes-10-00389-g014.jpg
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