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基于近红外反射光谱和化学计量学方法快速测定玉米秸秆中的木质纤维素。

Rapid determination of lignocellulose in corn stover based on near-infrared reflectance spectroscopy and chemometrics methods.

机构信息

College of Information and Electrical Engineering, Heilongjiang Bayi Agricultural University, Daqing 163319, PR China.

College of Engineering, Northeast Agricultural University, Harbin 150030, PR China.

出版信息

Bioresour Technol. 2021 Feb;321:124449. doi: 10.1016/j.biortech.2020.124449. Epub 2020 Nov 28.

Abstract

In this study, a rapid detection method based on near-infrared reflectance spectroscopy was proposed for measuring the contents of cellulose, hemicellulose and lignin in corn stover. In the basis of strategies of variable selection, feature extraction and nonlinear modeling, BiPLS-PCA-SVM was constructed using backward interval partial least squares combined with principal component analysis and support vector machine, which was used to improve the performance of spectral regression calibration model. For BiPLS-PCA-SVM model, the determination coefficients, root mean squared error and residual predictive deviation for the validation set were 0.906, 0.900% and 3.213 for cellulose; 0.987, 0.797% and 9.071 for hemicellulose; and 0.936, 0.264% and 4.024 for lignin, correspondingly. The results indicate that near-infrared reflectance spectroscopy combined with BiPLS-PCA-SVM can provide a reliable alternative strategy to detect contents of lignocellulosic components for pretreated corn stover in the anaerobic digestion process.

摘要

在这项研究中,提出了一种基于近红外反射光谱的快速检测方法,用于测量玉米秸秆中纤维素、半纤维素和木质素的含量。在变量选择、特征提取和非线性建模策略的基础上,采用反向区间偏最小二乘结合主成分分析和支持向量机构建了 BiPLS-PCA-SVM,以提高光谱回归校准模型的性能。对于 BiPLS-PCA-SVM 模型,纤维素、半纤维素和木质素的验证集的决定系数、均方根误差和预测残差偏差分别为 0.906、0.900%和 3.213;0.987、0.797%和 9.071;0.936、0.264%和 4.024。结果表明,近红外反射光谱结合 BiPLS-PCA-SVM 可以为预处理玉米秸秆在厌氧消化过程中木质纤维素成分含量的检测提供一种可靠的替代策略。

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