Nie Ben-Dian, Cao Bing-Yang, Guo Zeng-Yuan, Hua Yu-Chao
Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China.
Entropy (Basel). 2020 Feb 18;22(2):227. doi: 10.3390/e22020227.
Thermomass theory was developed to deal with the non-Fourier heat conduction phenomena involving the influence of heat inertia. However, its structure, derived from an analogy to fluid mechanics, requires further mathematical verification. In this paper, General Equation for Non-Equilibrium Reversible-Irreversible Coupling (GENERIC) framework, which is a geometrical and mathematical structure in nonequilibrium thermodynamics, was employed to verify the thermomass theory. At first, the thermomass theory was introduced briefly; then, the GENERIC framework was applied in the thermomass gas system with state variables, thermomass gas density and thermomass momentum , and the time evolution equations obtained from GENERIC framework were compared with those in thermomass theory. It was demonstrated that the equations generated by GENERIC theory were the same as the continuity and momentum equations in thermomass theory with proper potentials and eta-function. Thermomass theory gives a physical interpretation to the GENERIC theory in non-Fourier heat conduction phenomena. By combining these two theories, it was found that the Hamiltonian energy in reversible process and the dissipation potential in irreversible process could be unified into one formulation, i.e., the thermomass energy. Furthermore, via the framework of GENERIC, thermomass theory could be extended to involve more state variables, such as internal source term and distortion matrix term. Numerical simulations investigated the influences of the convective term and distortion matrix term in the equations. It was found that the convective term changed the shape of thermal energy distribution and enhanced the spreading behaviors of thermal energy. The distortion matrix implies the elasticity and viscosity of the thermomass gas.
热质量理论是为处理涉及热惯性影响的非傅里叶热传导现象而发展起来的。然而,其结构源于与流体力学的类比,需要进一步的数学验证。本文采用非平衡可逆-不可逆耦合通用方程(GENERIC)框架,这是一种非平衡热力学中的几何和数学结构,来验证热质量理论。首先,简要介绍了热质量理论;然后,将GENERIC框架应用于具有状态变量热质量气体密度和热质量动量的热质量气体系统,并将从GENERIC框架获得的时间演化方程与热质量理论中的方程进行比较。结果表明,GENERIC理论生成的方程与热质量理论中具有适当势和η函数的连续性方程和动量方程相同。热质量理论为非傅里叶热传导现象中的GENERIC理论提供了物理解释。通过结合这两种理论,发现可逆过程中的哈密顿能量和不可逆过程中的耗散势可以统一为一种表述,即热质量能量。此外,通过GENERIC框架,热质量理论可以扩展到包含更多状态变量,如内源项和畸变矩阵项。数值模拟研究了方程中对流项和畸变矩阵项的影响。结果发现,对流项改变了热能分布的形状并增强了热能的扩散行为。畸变矩阵意味着热质量气体的弹性和粘性。