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量子力学中的麦克斯韦妖

Maxwell's Demon in Quantum Mechanics.

作者信息

Shenker Orly, Hemmo Meir

机构信息

Department of Philosophy, The Hebrew University of Jerusalem Mount Scopus, Jerusalem 91905, Israel.

Department of Philosophy, University of Haifa, Haifa 31905, Israel.

出版信息

Entropy (Basel). 2020 Feb 27;22(3):269. doi: 10.3390/e22030269.

DOI:10.3390/e22030269
PMID:33286043
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7516722/
Abstract

Maxwell's Demon is a thought experiment devised by J. C. Maxwell in 1867 in order to show that the Second Law of thermodynamics is not universal, since it has a counter-example. Since the Second Law is taken by many to provide an arrow of time, the threat to its universality threatens the account of temporal directionality as well. Various attempts to "exorcise" the Demon, by proving that it is impossible for one reason or another, have been made throughout the years, but none of them were successful. We have shown (in a number of publications) by a general state-space argument that Maxwell's Demon is compatible with classical mechanics, and that the most recent solutions, based on Landauer's thesis, are not general. In this paper we demonstrate that Maxwell's Demon is also compatible with quantum mechanics. We do so by analyzing a particular (but highly idealized) experimental setup and proving that it violates the Second Law. Our discussion is in the framework of standard quantum mechanics; we give two separate arguments in the framework of quantum mechanics with and without the projection postulate. We address in our analysis the connection between measurement and erasure interactions and we show how these notions are applicable in the microscopic quantum mechanical structure. We discuss what might be the quantum mechanical counterpart of the classical notion of "macrostates", thus explaining why our Quantum Demon setup works not only at the micro level but also at the macro level, properly understood. One implication of our analysis is that the Second Law cannot provide a universal lawlike basis for an account of the arrow of time; this account has to be sought elsewhere.

摘要

麦克斯韦妖是J. C. 麦克斯韦在1867年设计的一个思想实验,旨在表明热力学第二定律并非普遍适用,因为它存在一个反例。由于许多人认为第二定律提供了一个时间箭头,其普遍性受到的威胁也对时间方向性的解释构成了威胁。多年来,人们进行了各种尝试来“驱除”这个妖,试图证明它由于某种原因是不可能存在的,但都没有成功。我们(在多篇出版物中)通过一个一般的状态空间论证表明,麦克斯韦妖与经典力学是兼容的,而且基于兰道尔理论的最新解决方案并不具有普遍性。在本文中,我们证明麦克斯韦妖也与量子力学兼容。我们通过分析一个特定的(但高度理想化的)实验装置并证明它违反了第二定律来做到这一点。我们的讨论是在标准量子力学的框架内进行的;我们在有和没有投影假设的量子力学框架内给出了两个独立的论证。我们在分析中探讨了测量与擦除相互作用之间的联系,并展示了这些概念如何应用于微观量子力学结构。我们讨论了经典“宏观态”概念在量子力学中的对应物可能是什么,从而解释了为什么我们的量子妖装置不仅在微观层面有效,而且在正确理解的宏观层面也有效。我们分析的一个含义是,第二定律不能为时间箭头的解释提供一个普遍的、类似定律的基础;这个解释必须在其他地方寻找。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d235/7516722/ebdde4e67993/entropy-22-00269-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d235/7516722/ebdde4e67993/entropy-22-00269-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d235/7516722/ebdde4e67993/entropy-22-00269-g001.jpg

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本文引用的文献

1
Information-to-work conversion by Maxwell's demon in a superconducting circuit quantum electrodynamical system.麦克斯韦妖在超导电路量子电动力学系统中的信息-工作转换。
Nat Commun. 2018 Mar 29;9(1):1291. doi: 10.1038/s41467-018-03686-y.
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Observing a quantum Maxwell demon at work.观测工作中的量子麦克斯韦妖。
Proc Natl Acad Sci U S A. 2017 Jul 18;114(29):7561-7564. doi: 10.1073/pnas.1704827114. Epub 2017 Jul 3.
3
Power generator driven by Maxwell's demon.由麦克斯韦妖驱动的发电机。
Nat Commun. 2017 May 16;8:15310. doi: 10.1038/ncomms15301.
4
Thermal Equilibrium of a Macroscopic Quantum System in a Pure State.处于纯态的宏观量子系统的热平衡。
Phys Rev Lett. 2015 Sep 4;115(10):100402. doi: 10.1103/PhysRevLett.115.100402.
5
Quantum mechanical evolution towards thermal equilibrium.朝向热平衡的量子力学演化。
Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Jun;79(6 Pt 1):061103. doi: 10.1103/PhysRevE.79.061103. Epub 2009 Jun 4.
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Extracting work from a single heat bath via vanishing quantum coherence.通过消失的量子相干性从单一热库中提取功。
Science. 2003 Feb 7;299(5608):862-4. doi: 10.1126/science.1078955. Epub 2003 Jan 2.