续环劳丹烷类化合物：萜类化合物结构多样性的生物合成 C-C 键断裂研究。
seco-Labdanes: A Study of Terpenoid Structural Diversity Resulting from Biosynthetic C-C Bond Cleavage.
机构信息
School of Chemical Sciences, University of Auckland, 23 Symonds Street, Auckland, 1010, New Zealand.
Maurice Wilkins Centre for Molecular Biodiscovery, University of Auckland, 23 Symonds Street, Auckland, 1010, New Zealand.
出版信息
Chemistry. 2021 Apr 12;27(21):6367-6389. doi: 10.1002/chem.202004574. Epub 2021 Feb 11.
The cleavage of a C-C bond is a complexity generating process, which complements oxidation and cyclisation events in the biosynthesis of terpenoids. This process leads to increased structural diversity in a cluster of related secondary metabolites by modification of the parent carbocyclic core. In this review, we highlight the diversifying effect of C-C bond cleavage by examining the literature related to seco-labdanes-a class of diterpenoids arising from such C-C bond cleavage events.
C-C 键的断裂是一个产生复杂性的过程，它与萜类化合物生物合成中的氧化和环化事件相辅相成。通过对母体碳环核心的修饰，该过程导致了一组相关的次生代谢物中结构多样性的增加。在这篇综述中，我们通过检查与 sec o- labdanes 相关的文献，强调了 C-C 键断裂的多样化效应，sec o- labdanes 是一类源自这种 C-C 键断裂事件的二萜类化合物。
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