Organic Chemistry Department, University of Geneva, 30 quai Ernest Ansermet, Geneva 1211, Switzerland.
Chem Soc Rev. 2021 Jan 21;50(2):1391-1406. doi: 10.1039/d0cs00449a. Epub 2020 Dec 9.
One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not only offer the inherent advantages of atom-, step- and redox-economy but also enable the preparation of value-added products that would be difficult to access by conventional methods. In this Review, we cover seminal and recent examples of tandem, sequential and domino processes, which incorporate the most attractive features of olefin isomerization.
一锅反应围绕着过渡金属催化的烯烃异构化展开，不仅具有原子经济性、步骤经济性和氧化还原经济性等固有优势，而且还能够制备通过传统方法难以获得的附加值产品。在这篇综述中，我们涵盖了串联、顺序和多米诺过程的开创性和最新实例，这些实例结合了烯烃异构化最具吸引力的特点。
