Ahmed Faruk, Dutta Basudeb, Mir Mohammad Hedayetullah
Department of Chemistry, Aliah University, New Town, Kolkata 700 156, India.
Dalton Trans. 2021 Jan 7;50(1):29-38. doi: 10.1039/d0dt03222k. Epub 2020 Dec 11.
Due to the easy functionality and structural diversity of coordination polymers (CPs) coupled with superior thermal stability, many researchers have been prompted to explore the opportunity of introducing these hybrid materials as active components in various electronic devices, such as light emitting diodes (LED), solar cells, field effect transistors (FET), and Schottky barrier diodes (SBD). Therefore, the judicious selection of the structural components of CPs is directly related to their structure-property relationship and applications. One-dimensional (1D) CPs have recently emerged as excellent electrical conductors and are gaining enormous attention owing to their simple chain-like coordination arrays. In this article, we review the rational design strategies for synthesising 1D CPs and also point out the structural factors that affect the charge transport properties as well as the electrical conductivity of these materials.
由于配位聚合物（CPs）具有易于实现的功能和结构多样性，以及出色的热稳定性，许多研究人员受到启发，探索将这些混合材料作为各种电子器件（如发光二极管（LED）、太阳能电池、场效应晶体管（FET）和肖特基势垒二极管（SBD））的活性成分的机会。因此，对CPs结构成分的明智选择直接关系到它们的结构-性能关系和应用。一维（1D）CPs最近已成为优异的电导体，并因其简单的链状配位阵列而受到广泛关注。在本文中，我们综述了合成1D CPs的合理设计策略，并指出了影响这些材料电荷传输性能以及电导率的结构因素。
