碲（II）/碲（III）催化的交叉脱氢C-N键形成反应
Tellurium(II)/Tellurium(III)-Catalyzed Cross-Dehydrogenative C-N Bond Formation.
作者信息
Cremer Christopher, Goswami Monalisa, Rank Christian K, de Bruin Bas, Patureau Frederic W
机构信息
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
Spark904 BV, Science Park 400, 1098 XH, Amsterdam, The Netherlands.
出版信息
Angew Chem Int Ed Engl. 2021 Mar 15;60(12):6451-6456. doi: 10.1002/anie.202015248. Epub 2021 Feb 4.
The Te /Te -catalyzed dehydrogenative C-H phenothiazination of challenging phenols featuring electron-withdrawing substituents under mild aerobic conditions and with high yields is described. These unexpected Te /Te radical catalytic properties were characterized by cyclic voltammetry, EPR spectroscopy, kinetic experiments, and DFT calculations.
本文描述了在温和有氧条件下，碲/碲催化具有吸电子取代基的挑战性酚类进行脱氢C-H吩噻嗪化反应，并获得高产率。通过循环伏安法、电子顺磁共振光谱、动力学实验和密度泛函理论计算对这些意外的碲/碲自由基催化性质进行了表征。
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