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金属有机框架和共价有机框架膜材料的当前趋势

Current Trends in Metal-Organic and Covalent Organic Framework Membrane Materials.

作者信息

Hosseini Monjezi Bahram, Kutonova Ksenia, Tsotsalas Manuel, Henke Sebastian, Knebel Alexander

机构信息

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.

Institute of Organic Chemistry (IOC), Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.

出版信息

Angew Chem Int Ed Engl. 2021 Jul 5;60(28):15153-15164. doi: 10.1002/anie.202015790. Epub 2021 Mar 3.

DOI:10.1002/anie.202015790
PMID:33332695
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8359388/
Abstract

Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have been thoroughly investigated with regards to applications in gas separation membranes in the past years. More recently, new preparation methods for MOFs and COFs as particles and thin-film membranes, as well as for mixed-matrix membranes (MMMs) have been developed. We will highlight novel processes and highly functional materials: Zeolitic imidazolate frameworks (ZIFs) can be transformed into glasses and we will give an insight into their use for membranes. In addition, liquids with permanent porosity offer solution processability for the manufacture of extremely potent MMMs. Also, MOF materials influenced by external stimuli give new directions for the enhancement of performance by in situ techniques. Presently, COFs with their large pores are useful in quantum sieving applications, and by exploiting the stacking behavior also molecular sieving COF membranes are possible. Similarly, porous polymers can be constructed using MOF templates, which then find use in gas separation membranes.

摘要

在过去几年中，金属有机框架材料（MOFs）和共价有机框架材料（COFs）在气体分离膜领域的应用已得到深入研究。最近，已开发出用于制备作为颗粒和薄膜的MOFs和COFs以及混合基质膜（MMMs）的新方法。我们将重点介绍新颖的工艺和高功能材料：沸石咪唑酯骨架材料（ZIFs）可转化为玻璃，我们将深入探讨其在膜方面的应用。此外，具有永久孔隙率的液体为制造极具潜力的混合基质膜提供了溶液可加工性。而且，受外部刺激影响的MOF材料为通过原位技术提高性能指明了新方向。目前，具有大孔的COFs在量子筛分应用中很有用，通过利用堆积行为也有可能制备分子筛分COF膜。同样，可以使用MOF模板构建多孔聚合物，然后将其用于气体分离膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/341d/8359388/3a8ac8bf23d7/ANIE-60-15153-g011.jpg
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