氢键镍（I）配合物。
Hydrogen-bonded nickel(I) complexes.
机构信息
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.
H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA.
出版信息
Chem Commun (Camb). 2021 Jan 26;57(6):753-756. doi: 10.1039/d0cc07216h.
Abstract
A series of nickel(ii) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(i) state provided access to an unusual nickel(i) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.
摘要
一系列镍（II）三（2-吡啶甲基）胺（TPA）配合物具有附加的氢键（H 键）到卤化物（F，Cl，Br），并对其进行了合成和表征。还原为镍（I）态提供了一种不寻常的镍（I）氟化物配合物，该配合物由氢键稳定，从而能够进行结构和光谱表征。
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