Santoro Gonzalo, Sobrado Jesús M, Tajuelo-Castilla Guillermo, Accolla Mario, Martínez Lidia, Azpeitia Jon, Lauwaet Koen, Cernicharo José, Ellis Gary J, Martín-Gago José Ángel
Instituto de Ciencia de Materiales de Madrid (ICMM, CSIC), Materials Science Factory, Structure of Nanoscopic Systems Group, c/Sor Juana Inés de la Cruz 3, E-28049 Cantoblanco, Madrid, Spain.
Centro de Astrobiología (CAB, INTA-CSIC), Crta. de Torrejón a Ajalvir km 4, E-28850 Torrejón de Ardoz, Madrid, Spain.
Rev Sci Instrum. 2020 Dec 1;91(12):124101. doi: 10.1063/5.0027920.
Laboratory astrochemistry aims at simulating, in the laboratory, some of the chemical and physical processes that operate in different regions of the universe. Amongst the diverse astrochemical problems that can be addressed in the laboratory, the evolution of cosmic dust grains in different regions of the interstellar medium (ISM) and its role in the formation of new chemical species through catalytic processes present significant interest. In particular, the dark clouds of the ISM dust grains are coated by icy mantles and it is thought that the ice-dust interaction plays a crucial role in the development of the chemical complexity observed in space. Here, we present a new ultra-high vacuum experimental station devoted to simulating the complex conditions of the coldest regions of the ISM. The INFRA-ICE machine can be operated as a standing alone setup or incorporated in a larger experimental station called Stardust, which is dedicated to simulate the formation of cosmic dust in evolved stars. As such, INFRA-ICE expands the capabilities of Stardust allowing the simulation of the complete journey of cosmic dust in space, from its formation in asymptotic giant branch stars to its processing and interaction with icy mantles in molecular clouds. To demonstrate some of the capabilities of INFRA-ICE, we present selected results on the ultraviolet photochemistry of undecane (CH) at 14 K. Aliphatics are part of the carbonaceous cosmic dust, and recently, aliphatics and short n-alkanes have been detected in situ in the comet 67P/Churyumov-Gerasimenko.
实验室天体化学旨在在实验室中模拟宇宙不同区域发生的一些化学和物理过程。在实验室中可以解决的各种天体化学问题中,星际介质(ISM)不同区域中宇宙尘埃颗粒的演化及其在通过催化过程形成新化学物种中所起的作用引起了人们的极大兴趣。特别是,ISM尘埃颗粒的暗云被冰质包层覆盖,人们认为冰-尘相互作用在太空中观察到的化学复杂性发展中起着关键作用。在这里,我们展示了一个新的超高真空实验站,专门用于模拟ISM最冷区域的复杂条件。INFRA-ICE机器既可以作为独立装置运行,也可以并入一个名为“星尘”的更大实验站,该实验站致力于模拟演化恒星中宇宙尘埃的形成。因此,INFRA-ICE扩展了“星尘”的功能,允许模拟宇宙尘埃在太空中的完整旅程,从其在渐近巨星分支恒星中的形成到其在分子云中与冰质包层的处理和相互作用。为了展示INFRA-ICE的一些功能,我们展示了在14K下正十一烷(CH)的紫外光化学的选定结果。脂肪族是含碳宇宙尘埃的一部分,最近,在彗星67P/丘留莫夫-格拉西缅科中现场检测到了脂肪族和短链正构烷烃。