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欧洲同步辐射装置(ESRF)的ROBL-II:用于锕系元素研究的同步加速器工具箱。

ROBL-II at ESRF: a synchrotron toolbox for actinide research.

作者信息

Scheinost Andreas C, Claussner Juergen, Exner Joerg, Feig Manuel, Findeisen Stefan, Hennig Christoph, Kvashnina Kristina O, Naudet Damien, Prieur Damien, Rossberg Andre, Schmidt Moritz, Qiu Canrong, Colomp Patrick, Cohen Cedric, Dettona Eric, Dyadkin Vadim, Stumpf Thorsten

机构信息

The Rossendorf Beamline (BM20), European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38043 Grenoble, France.

Department of Research Technology, Helmholtz Zentrum Dresden Rossendorf, Bautzner Landstrasse 400, 01328 Dresden, Germany.

出版信息

J Synchrotron Radiat. 2021 Jan 1;28(Pt 1):333-349. doi: 10.1107/S1600577520014265.

Abstract

ROBL-II provides four different experimental stations to investigate actinide and other alpha- and beta-emitting radionuclides at the new EBS storage ring of ESRF within an energy range of 3 to 35 keV. The XAFS station consists of a highly automatized, high sample throughput installation in a glovebox, to measure EXAFS and conventional XANES of samples routinely at temperatures down to 10 K, and with a detection limit in the sub-p.p.m. range. The XES station with its five bent-crystal analyzer, Johann-type setup with Rowland circles of 1.0 and 0.5 m radii provides high-energy resolution fluorescence detection (HERFD) for XANES, XES, and RIXS measurements, covering both actinide L and M edges together with other elements accessible in the 3 to 20 keV energy range. The six-circle heavy duty goniometer of XRD-1 is equipped for both high-resolution powder diffraction as well as surface-sensitive CTR and RAXR techniques. Single crystal diffraction, powder diffraction with high temporal resolution, as well as X-ray tomography experiments can be performed at a Pilatus 2M detector stage (XRD-2). Elaborate radioprotection features enable a safe and easy exchange of samples between the four different stations to allow the combination of several methods for an unprecedented level of information on radioactive samples for both fundamental and applied actinide and environmental research.

摘要

ROBL-II在欧洲同步辐射装置(ESRF)新的电子束储存环中提供了四个不同的实验站,用于在3至35 keV的能量范围内研究锕系元素以及其他发射α和β射线的放射性核素。XAFS站由手套箱内高度自动化、高样品通量的装置组成,可在低至10 K的温度下常规测量样品的扩展X射线吸收精细结构(EXAFS)和传统X射线吸收近边结构(XANES),检测限在百万分之一以下。XES站配备了五个弯晶分析仪,采用半径为1.0米和0.5米的罗兰圆的约翰型装置,为XANES、XES和共振非弹性X射线散射(RIXS)测量提供高能量分辨率荧光检测(HERFD),涵盖锕系元素的L和M边以及3至20 keV能量范围内的其他可及元素。XRD-1的六圆重型测角仪配备了高分辨率粉末衍射以及表面敏感的临界角反射(CTR)和反射吸收X射线衍射(RAXR)技术。单晶衍射、具有高时间分辨率的粉末衍射以及X射线断层扫描实验可在Pilatus 2M探测器平台(XRD-2)上进行。精心设计的辐射防护功能使得在四个不同实验站之间能够安全、便捷地交换样品,从而可以将多种方法结合起来,以前所未有的程度获取关于放射性样品的信息,用于基础和应用的锕系元素及环境研究。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3dfa/7842221/ef38dce5fd38/s-28-00333-fig1.jpg

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