Tecnologico de Monterrey, Campus Toluca, Avenida Eduardo Monroy Cárdenas 2000 San Antonio Buenavista, 50110, Toluca de Lerdo, Mexico; Gdansk University of Technology, Faculty of Chemistry, Department of Process, Engineering and Chemical Technology, 11/12 Narutowicza St., 80-233, Gdansk, Poland.
Tecnologico de Monterrey, Campus Querétaro, Avenida Epigmenio González 500, Santiago de Querétaro, 76130, Mexico.
Chemosphere. 2021 May;270:129421. doi: 10.1016/j.chemosphere.2020.129421. Epub 2020 Dec 28.
Membranes, as the primary separation element of membrane-based processes, have greatly attracted the attention of researchers in several water treatment applications, including wastewater treatment, water purification, water disinfection, toxic and non-toxic chemical molecules, heavy metals, among others. Today, the removal of heavy metals from water has become challenging, in which chemical engineers are approaching new materials in membrane technologies. Therefore, the current review elucidates the progress of using different concepts of membranes and potential novel materials for such separations, identifying that polymeric membranes can exhibit a removal efficiency from 77 up to 99%; while novel nanocomposite membranes are able to offer complete removal of heavy metals (up to 100%), together with unprecedented permeation rates (from 80 up to 1, 300 L m h). Thereby, the review also addresses the highlighted literature survey of using polymeric and nanocomposite membranes for heavy metal removal, highlighting the relevant insights and denoted metal uptake mechanisms. Moreover, it gives up-to-date information related to those novel nanocomposite materials and their contribution to heavy metals separation. Finally, the concluding remarks, future perspectives, and strategies for new researchers in the field are given according to the recent findings of this comprehensive review.
膜作为膜基过程的主要分离元件,在包括废水处理、水净化、水消毒、有毒和无毒化学分子、重金属等在内的多种水处理应用中引起了研究人员的极大关注。如今,从水中去除重金属已变得极具挑战性,为此化学工程师在膜技术中采用了新材料。因此,本综述阐述了使用不同膜概念和潜在新型材料进行此类分离的进展,发现聚合物膜的去除效率可达 77%至 99%;而新型纳米复合膜能够实现重金属的完全去除(高达 100%),同时具有前所未有的渗透速率(80 升至 1300 L·m-2·h-1)。因此,该综述还重点介绍了使用聚合物和纳米复合膜去除重金属的文献调查,强调了相关的见解和指定的金属吸收机制。此外,它还提供了与这些新型纳米复合材料及其在重金属分离方面的贡献相关的最新信息。最后,根据这篇全面综述的最新发现,给出了该领域新研究人员的结论性意见、未来展望和策略。