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渗透驱动膜过程中的传质

Mass Transport in Osmotically Driven Membrane Processes.

作者信息

Xie Peng, Cath Tzahi Y, Ladner David A

机构信息

Department of Environmental Engineering and Earth Sciences, Clemson University, Clemson, SC 29625, USA.

Department of Civil and Environmental Engineering, Colorado School Mines, Golden, CO 80401, USA.

出版信息

Membranes (Basel). 2021 Jan 1;11(1):29. doi: 10.3390/membranes11010029.

DOI:10.3390/membranes11010029
PMID:33401463
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7824693/
Abstract

Forward osmosis (FO) and pressure retarded osmosis (PRO) are the two operational modes for osmotically driven membrane processes (ODMPs). ODMPs have gained increasing popularity in the laboratory over the years; however, OMDPs have not been applied in very many cases at full scale because they are still emerging technologies that require further development. Computational fluid dynamics (CFD) modeling coupled with solute transport evaluation provides a tool to study hydrodynamics and concentration polarization in FO and PRO. In this study a series of models were developed to predict water flux. The simulation results of empty-channel (with no feed spacer) membrane cells were verified by comparison with experimental results, showing that CFD simulation with solute transport is a reliable tool. Ensuing 2D and 3D models were built to study the impact of feed spacers on the velocity and concentration distribution inside the flow channels, and investigate whether the presence of spacers would enable enhancement of water flux. The results showed that spacers could change the concentration and velocity profile and they could reduce or enhance water flux depending on the inlet flow velocity and distance between the membrane and spacer.

摘要

正向渗透(FO)和压力延迟渗透(PRO)是渗透驱动膜过程(ODMPs)的两种操作模式。多年来,ODMPs在实验室中越来越受欢迎;然而,由于它们仍是需要进一步发展的新兴技术,在很多情况下尚未得到大规模应用。计算流体动力学(CFD)建模结合溶质输运评估提供了一种研究FO和PRO中流体动力学和浓差极化的工具。在本研究中,开发了一系列模型来预测水通量。通过与实验结果比较,验证了无进料间隔物的空通道膜池的模拟结果,表明结合溶质输运的CFD模拟是一种可靠的工具。随后建立了二维和三维模型,以研究进料间隔物对流道内速度和浓度分布的影响,并研究间隔物的存在是否能提高水通量。结果表明,间隔物可以改变浓度和速度分布,并且根据入口流速以及膜与间隔物之间的距离,它们可以降低或提高水通量。

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本文引用的文献

1
A Review of CFD Modelling and Performance Metrics for Osmotic Membrane Processes.渗透膜过程的计算流体动力学建模与性能指标综述
Membranes (Basel). 2020 Oct 15;10(10):285. doi: 10.3390/membranes10100285.
2
Development and characterization of 3D-printed feed spacers for spiral wound membrane systems.3D 打印螺旋卷式膜系统用给料间隔物的开发与特性研究。
Water Res. 2016 Mar 15;91:55-67. doi: 10.1016/j.watres.2015.12.052. Epub 2016 Jan 2.
3
Validation and Analysis of Forward Osmosis CFD Model in Complex 3D Geometries.复杂三维几何结构中正向渗透计算流体动力学模型的验证与分析
Membranes (Basel). 2012 Nov 9;2(4):764-82. doi: 10.3390/membranes2040764.
4
Impact of spacer thickness on biofouling in forward osmosis.间隔厚度对正向渗透生物污染的影响。
Water Res. 2014 Jun 15;57:223-33. doi: 10.1016/j.watres.2014.03.046. Epub 2014 Mar 27.
5
Forward and pressure retarded osmosis: potential solutions for global challenges in energy and water supply.正向和压力延迟渗透:能源和水供应方面全球挑战的潜在解决方案。
Chem Soc Rev. 2013 Aug 21;42(16):6959-89. doi: 10.1039/c3cs60051c.
6
Performance of a novel osmotic membrane bioreactor (OMBR) system: flux stability and removal of trace organics.新型渗透膜生物反应器(OMBR)系统的性能:通量稳定性和痕量有机物去除。
Bioresour Technol. 2012 Jun;113:201-6. doi: 10.1016/j.biortech.2012.01.082. Epub 2012 Jan 25.
7
High performance thin-film composite forward osmosis membrane.高性能薄膜复合正向渗透膜。
Environ Sci Technol. 2010 May 15;44(10):3812-8. doi: 10.1021/es1002555.
8
Biofouling of spiral-wound nanofiltration and reverse osmosis membranes: a feed spacer problem.螺旋缠绕式纳滤和反渗透膜的生物污染:进水间隔物问题
Water Res. 2009 Feb;43(3):583-94. doi: 10.1016/j.watres.2008.11.019. Epub 2008 Nov 27.