Debiossac Maxime, Pan Peng, Roncin Philippe
Université Paris-Saclay, CNRS, Institut des Sciences Moléculaires d'Orsay (ISMO), 91405 Orsay, France.
Phys Chem Chem Phys. 2021 Apr 7;23(13):7615-7636. doi: 10.1039/d0cp05476c. Epub 2021 Jan 6.
Grazing incidence fast atom diffraction (GIFAD) at surfaces has made rapid progress and has established itself as a surface analysis tool where effective energy E of the motion towards the surface is in the same range as that in thermal energy atom scattering (TEAS). To better compare the properties of both techniques, we use the diffraction patterns of helium and neon atoms impinging on a LiF (001) surface as a model system. E-Scan, θ-scan, and φ-scan are presented where the primary beam energy E is varied between a few hundred eV up to five keV, the angle of incidence θ between 0.2 and 2° and the azimuthal angle φ around 360°. The resulting diffraction charts are analyzed in terms of high and low values of effective energy E. The former provides high resolution at the positions of the surface atoms and the attached repulsive interaction potentials while the second is sensitive to the attractive forces towards the surface. The recent progress of inelastic diffraction is briefly presented.
掠入射快速原子衍射(GIFAD)在表面分析领域已取得快速进展,并已成为一种表面分析工具,其朝向表面运动的有效能量E与热能原子散射(TEAS)中的能量处于同一范围。为了更好地比较这两种技术的特性,我们将撞击LiF(001)表面的氦原子和氖原子的衍射图案用作模型系统。展示了E扫描、θ扫描和φ扫描,其中初级束能量E在几百电子伏特到5千电子伏特之间变化,入射角θ在0.2°到2°之间,方位角φ约为360°。根据有效能量E的高值和低值对所得衍射图进行分析。前者在表面原子位置和附着的排斥相互作用势方面提供高分辨率,而后者对朝向表面的吸引力敏感。简要介绍了非弹性衍射的最新进展。