Université Paris-Saclay, CNRS, Institut des Sciences Moléculaires d'Orsay (ISMO), 91405 Orsay, France.
Phys Chem Chem Phys. 2022 May 25;24(20):12319-12328. doi: 10.1039/d2cp00829g.
Grazing incidence fast atom diffraction at crystal surfaces (GIFAD or FAD) has demonstrated coherent diffraction both at effective energies close to one eV ( ≈ 14 pm for He) and at elevated surface temperatures offering high topological resolution and real time monitoring of growth processes. This is explained by a favorable Debye-Waller factor specific to the multiple collision regime of grazing incidence. This paper presents the first extensive evaluation of the temperature behavior between 177 and 1017 K on a LiF surface. Similarly to diffraction at thermal energies (TEAS), an exponential attenuation of the elastic intensity is observed but, contrarily to TEAS, the maximum coherence is not directly reduced by the attraction forces that increase the effective impact energy. It is more influenced by the surface stiffness and appears very sensitive to surface defects.
晶体表面掠入射快速原子衍射(GIFAD 或 FAD)在有效能量接近 1eV(对于 He 约为 14pm)时表现出相干衍射,并且在升高的表面温度下提供高拓扑分辨率和生长过程的实时监测。这可以通过掠入射的多次碰撞模式特有的有利德拜-沃勒因子来解释。本文首次对 LiF 表面在 177 至 1017K 温度范围内的行为进行了广泛评估。与热能(TEAS)衍射类似,观察到弹性强度的指数衰减,但与 TEAS 相反,最大相干性不会直接被增加有效冲击能量的吸引力所降低。它更多地受到表面刚度的影响,并且对表面缺陷非常敏感。