Hepsağ Fatma, Kizildeniz Tefide
School of Applied Sciences, Department of Food Technology, Korkut Ata University, Kadirli Campus, 80750, Osmaniye, Turkey.
Faculty of Agricultural Sciences and Technologies, Biosystem Engineering Department, Niğde Ömer Halisdemir University, Merkez Campus, 51240, Niğde, Turkey.
Environ Sci Pollut Res Int. 2021 May;28(18):22551-22562. doi: 10.1007/s11356-020-12232-7. Epub 2021 Jan 9.
This research aims at assessing the health risks associated with pesticide residues in greenhouse grown tomato production in the Mediterranean Region of Turkey. A multiresidue method based on modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) was used for sample preparation that is applied for pesticide detection from extraction of tomato samples in the methodology generated by The Association of Official Analytical Chemists (AOAC) Official Method. The restrain of the quantification varied from 0.002 to 0.009 mg kg. The validated data exposed both adequate recoveries, repeatability and reproducibility, including accomplished all other requirements of the European DG SANTE/12682/2019 Guideline. This study divulges that tomatoes cultivated in greenhouse demonstrate 61.5% of samples with one or various pesticide residues. The maximum permitted residue level of above the EU DG Guideline was in 12.2% of the samples. The main determined pesticide residues on the tomatoes cultivated in greenhouse were identified as chlorpyrifos methyl, cyfluthrin, deltamethrin, and acetamiprid. Chlorpyrifos methyl (9.5%), cyfluthrin (6.6%), deltamethrin (5.5%), and acetamiprid (3.2%) were recognized as the most conducing residues to the hazard index (HI). The HI was 9.5% for adults and 11.02% for children (3 to <10 years). The major contributor of the HI was chlorpyrifos in both.
本研究旨在评估土耳其地中海地区温室种植番茄生产中与农药残留相关的健康风险。采用基于改良QuEChERS（快速、简便、廉价、有效、耐用且安全）的多残留方法进行样品制备，该方法应用于美国官方分析化学家协会（AOAC）官方方法所生成的方法中番茄样品的农药检测提取。定量限在0.002至0.009毫克/千克之间。经过验证的数据显示出足够的回收率、重复性和再现性，包括满足了欧洲DG SANTE/12682/2019指南的所有其他要求。本研究表明，温室种植的番茄中有61.5%的样品含有一种或多种农药残留。超过欧盟DG指南最大残留限量的样品占12.2%。温室种植番茄上主要检测到的农药残留被确定为甲基毒死蜱、氟氯氰菊酯、溴氰菊酯和啶虫脒。甲基毒死蜱（9.5%）、氟氯氰菊酯（6.6%）、溴氰菊酯（5.5%）和啶虫脒（3.2%）被认为是对危害指数（HI）贡献最大的残留。成人的危害指数为9.5%，儿童（3至<10岁）为11.02%。两者中危害指数的主要贡献者均为毒死蜱。
