Antov Petar, Savov Viktor, Krišťák Ľuboš, Réh Roman, Mantanis George I
Department of Mechanical Wood Technology, Faculty of Forest Industry, University of Forestry, 1797 Sofia, Bulgaria.
Faculty of Wood Sciences and Technology, Technical University in Zvolen, T. G. Masaryka 24, 960 01 Zvolen, Slovakia.
Polymers (Basel). 2021 Jan 10;13(2):220. doi: 10.3390/polym13020220.
The potential of producing eco-friendly, formaldehyde-free, high-density fiberboard (HDF) panels from hardwood fibers bonded with urea-formaldehyde (UF) resin and a novel ammonium lignosulfonate (ALS) is investigated in this paper. HDF panels were fabricated in the laboratory by applying a very low UF gluing factor (3%) and ALS content varying from 6% to 10% (based on the dry fibers). The physical and mechanical properties of the fiberboards, such as water absorption (WA), thickness swelling (TS), modulus of elasticity (MOE), bending strength (MOR), internal bond strength (IB), as well as formaldehyde content, were determined in accordance with the corresponding European standards. Overall, the HDF panels exhibited very satisfactory physical and mechanical properties, fully complying with the standard requirements of HDF for use in load-bearing applications in humid conditions. Markedly, the formaldehyde content of the laboratory fabricated panels was extremely low, ranging between 0.7-1.0 mg/100 g, which is, in fact, equivalent to the formaldehyde release of natural wood.
本文研究了利用脲醛(UF)树脂和新型木质素磺酸铵(ALS)粘结硬木纤维生产环保、无甲醛高密度纤维板(HDF)的潜力。在实验室中,通过应用极低的UF胶合因子(3%)和6%至10%(基于干纤维)的ALS含量来制造HDF板。根据相应的欧洲标准测定了纤维板的物理和力学性能,如吸水率(WA)、厚度膨胀率(TS)、弹性模量(MOE)、抗弯强度(MOR)、内结合强度(IB)以及甲醛含量。总体而言,HDF板表现出非常令人满意的物理和力学性能,完全符合在潮湿条件下用于承重应用的HDF标准要求。值得注意的是,实验室制造的板材甲醛含量极低,在0.7 - 1.0毫克/100克之间,实际上等同于天然木材的甲醛释放量。