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电化学木质素转化。

Electrochemical Lignin Conversion.

机构信息

Renewable Resources and Enabling Sciences Center, National Renewable Energy Laboratory (NREL), Golden, CO 80401, USA.

School of Chemical & Biomolecular Engineering and Renewable Bioproducts Institute, Georgia Institute of Technology, 500 10th Street N.W., Atlanta, GA 303320620, USA.

出版信息

ChemSusChem. 2020 Sep 7;13(17):4318-4343. doi: 10.1002/cssc.202001187. Epub 2020 Aug 11.

Abstract

Lignin is the largest source of renewable aromatic compounds, making the recovery of aromatic compounds from this material a significant scientific goal. Recently, many studies have reported on lignin depolymerization and upgrading strategies. Electrochemical approaches are considered to be low cost, reagent free, and environmentally friendly, and can be carried out under mild reaction conditions. In this Review, different electrochemical lignin conversion strategies, including electrooxidation, electroreduction, hybrid electro-oxidation and reduction, and combinations of electrochemical and other processes (e. g., biological, solar) for lignin depolymerization and upgrading are discussed in detail. In addition to lignin conversion, electrochemical lignin fractionation from biomass and black liquor is also briefly discussed. Finally, the outlook and challenges for electrochemical lignin conversion are presented.

摘要

木质素是可再生芳香族化合物的最大来源,因此从该材料中回收芳香族化合物是一个重要的科学目标。最近,许多研究都报道了木质素解聚和升级策略。电化学方法被认为具有成本低、试剂免费和环境友好的特点,并且可以在温和的反应条件下进行。在这篇综述中,详细讨论了不同的电化学木质素转化策略,包括电氧化、电还原、电氧化和还原的混合、以及电化学和其他工艺(例如生物、太阳能)的组合,用于木质素的解聚和升级。除了木质素转化,还简要讨论了从生物质和黑液中电化学分离木质素的问题。最后,提出了电化学木质素转化的展望和挑战。

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