Wang Tongzhou, Cao Xuejie, Jiao Lifang
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), College of Chemistry Nankai University, Tianjin, 300071, China.
Small. 2021 Jun;17(22):e2004398. doi: 10.1002/smll.202004398. Epub 2021 Jan 18.
Electrochemical devices, as renewable and clean energy systems, display a great potential to meet the sustainable development in the future. However, well-designed and highly efficient electrocatalysts are the technological dilemmas that retard their practical applications. Metal-organic frameworks (MOFs) derived electrocatalysts exhibit tunable structure and intriguing activity and have received intensive investigation in recent years. In this review, the recent progress of MOFs-derived carbon-based single atoms (SAs) and metal nanoparticles (NPs) catalysts for energy-related electrocatalysis is summarized. The effects of synthesis strategy, coordination environment, morphology, and composition on the catalytic activity are highlighted. Furthermore, these SAs and metal NPs catalysts for the applications of electrocatalysis (hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, carbon dioxide reduction reaction, and nitrogen reduction reaction) are overviewed. Finally, some current challenges and foresighted ideas for MOFs-derived carbon-based metal electrocatalysts are presented.
电化学装置作为可再生和清洁能源系统，在满足未来可持续发展方面显示出巨大潜力。然而，设计良好且高效的电催化剂是阻碍其实际应用的技术难题。金属有机框架（MOF）衍生的电催化剂具有可调节的结构和引人注目的活性，近年来受到了广泛研究。在本综述中，总结了MOF衍生的碳基单原子（SA）和金属纳米颗粒（NP）催化剂在能源相关电催化方面的最新进展。突出了合成策略、配位环境、形态和组成对催化活性的影响。此外，还概述了这些SA和金属NP催化剂在电催化应用（析氢反应、析氧反应、氧还原反应、二氧化碳还原反应和氮还原反应）中的情况。最后，提出了MOF衍生的碳基金属电催化剂目前面临的一些挑战和前瞻性想法。
