Wang Hao-Fan, Chen Liyu, Pang Huan, Kaskel Stefan, Xu Qiang
AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
Chem Soc Rev. 2020 Mar 7;49(5):1414-1448. doi: 10.1039/c9cs00906j. Epub 2020 Feb 10.
Oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are three key reactions for the development of green and sustainable energy systems. Efficient electrocatalysts for these reactions are highly desired to lower their overpotentials and promote practical applications of related energy devices. Metal-organic frameworks (MOFs) have recently emerged as precursors to fabricate carbon-based electrocatalysts with high electrical conductivity and uniformly distributed active sites. In this review, the current progress of MOF-derived carbon-based materials for ORR/OER/HER electrocatalysis is presented. Materials design strategies of MOF-derived carbon-based materials are firstly summarized to show the rich possibilities of the morphology and composition of MOF-derived carbon-based materials. A wide range of applications based on these materials for ORR, OER, HER and multifunctional electrocatalysis are discussed, with an emphasis on the required features of MOF-derived carbon-based materials for the electrocatalysis of corresponding reactions. Finally, perspectives on the development of MOF-derived carbon-based materials for ORR, OER and HER electrocatalysis are provided.
氧还原反应（ORR）、析氧反应（OER）和析氢反应（HER）是绿色可持续能源系统发展的三个关键反应。人们迫切需要用于这些反应的高效电催化剂，以降低其过电位并促进相关能源装置的实际应用。金属有机框架（MOF）最近已成为制备具有高电导率和活性位点均匀分布的碳基电催化剂的前驱体。在这篇综述中，介绍了MOF衍生的碳基材料用于ORR/OER/HER电催化的当前进展。首先总结了MOF衍生的碳基材料的材料设计策略，以展示MOF衍生的碳基材料在形态和组成方面的丰富可能性。讨论了基于这些材料在ORR、OER、HER和多功能电催化方面的广泛应用，重点强调了MOF衍生的碳基材料用于相应反应电催化所需的特性。最后，提供了关于MOF衍生的碳基材料用于ORR、OER和HER电催化发展的展望。
