含二茂铁的氧化还原响应型聚(2-恶唑啉)。
Ferrocene containing redox-responsive poly(2-oxazoline)s.
机构信息
Laboratory of Organic and Macromolecular Chemistry (IOMC) Friedrich Schiller University Jena, Humboldtstr. 10, Jena 07743, Germany.
出版信息
Chem Commun (Camb). 2021 Feb 7;57(11):1308-1311. doi: 10.1039/d0cc07830a. Epub 2021 Jan 18.
A new monomer, 2-ferrocene-ethyl-2-oxazoline, was copolymerized with 2-alkyl-2-oxazolines. The cationic ring opening polymerization (CROP) of 2-oxazolines allows the synthesis of well-defined copolymers with adjustable molar masses as well as end-group control, which was also evident from kinetic studies. The utilization of this new comonomer led to redox-active polymers as proven by UV-VIS-measurements and cyclic-voltammetry.
一种新型单体，2-二茂铁基乙基-2-恶唑啉，与 2-烷基-2-恶唑啉共聚。2-恶唑啉的阳离子开环聚合（CROP）允许合成具有可调分子量和端基控制的具有明确结构的共聚物，这也从动力学研究中得到了证明。这种新单体的使用导致了氧化还原活性聚合物，正如 UV-VIS 测量和循环伏安法所证明的那样。
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