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通过超声处理改善热塑性淀粉/白云石生物复合薄膜的拉伸和撕裂性能

Improving the Tensile and Tear Properties of Thermoplastic Starch/Dolomite Biocomposite Film through Sonication Process.

作者信息

Osman Azlin Fazlina, Siah Lilian, Alrashdi Awad A, Ul-Hamid Anwar, Ibrahim Ismail

机构信息

Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Arau 02600, Malaysia.

Biomedical and Nanotechnology Research Group, Center of Excellence Geopolymer and Green Technology (CEGeoGTech), Universiti Malaysia Perlis (UniMAP), Arau 02600, Malaysia.

出版信息

Polymers (Basel). 2021 Jan 15;13(2):274. doi: 10.3390/polym13020274.

DOI:10.3390/polym13020274
PMID:33467685
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7830891/
Abstract

In this work, dolomite filler was introduced into thermoplastic starch (TPS) matrix to form TPS-dolomite (TPS-DOL) biocomposites. TPS-DOL biocomposites were prepared at different dolomite loadings (1 wt%, 2 wt%, 3 wt%, 4 wt% and 5 wt%) and by using two different forms of dolomite (pristine (DOL(P) and sonicated dolomite (DOL(U)) via the solvent casting technique. The effects of dolomite loading and sonication process on the mechanical properties of the TPS-DOL biocomposites were analyzed using tensile and tear tests. The chemistry aspect of the TPS-DOL biocomposites was analyzed using Fourier transform infrared spectroscopy (FTIR) and X-Ray Diffraction (XRD) analysis. According to the mechanical data, biocomposites with a high loading of dolomite (4 and 5 wt%) possess greater tensile and tear properties as compared to the biocomposites with a low loading of dolomite (1 and 2 wt%). Furthermore, it is also proved that the TPS-DOL(U) biocomposites have better mechanical properties when compared to the TPS-DOL(P) biocomposites. Reduction in the dolomite particle size upon the sonication process assisted in its dispersion and distribution throughout the TPS matrix. Thus, this led to the improvement of the tensile and tear properties of the biocomposite. Based on the findings, it is proven that the sonication process is a simple yet beneficial technique in the production of the TPS-dolomite biocomposites with improved tensile and tear properties for use as packaging film.

摘要

在这项工作中,将白云石填料引入热塑性淀粉(TPS)基体中,以形成TPS-白云石(TPS-DOL)生物复合材料。通过溶剂浇铸技术,在不同白云石负载量(1 wt%、2 wt%、3 wt%、4 wt%和5 wt%)下,使用两种不同形式的白云石(原始白云石(DOL(P))和超声处理后的白云石(DOL(U)))制备TPS-DOL生物复合材料。使用拉伸和撕裂试验分析白云石负载量和超声处理工艺对TPS-DOL生物复合材料力学性能的影响。使用傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)分析来研究TPS-DOL生物复合材料的化学特性。根据力学数据,与低白云石负载量(1和2 wt%)的生物复合材料相比,高白云石负载量(4和5 wt%)的生物复合材料具有更高的拉伸和撕裂性能。此外,还证明了与TPS-DOL(P)生物复合材料相比,TPS-DOL(U)生物复合材料具有更好的力学性能。超声处理过程中白云石粒径的减小有助于其在整个TPS基体中的分散和分布。因此,这导致了生物复合材料拉伸和撕裂性能的提高。基于这些发现,证明了超声处理过程是一种简单而有益的技术,可用于生产具有改进拉伸和撕裂性能的TPS-白云石生物复合材料,用作包装薄膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/8f113b9f72a4/polymers-13-00274-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/6cbb647d6fc0/polymers-13-00274-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/c1f0a1c4c494/polymers-13-00274-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/d42687013254/polymers-13-00274-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/ddf4b317fa21/polymers-13-00274-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/7a0ed299d6a4/polymers-13-00274-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/1cefec88e259/polymers-13-00274-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/aed6b5ff378a/polymers-13-00274-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/4a23af5654b7/polymers-13-00274-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/9bad4c40eacc/polymers-13-00274-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/4724e33b9da2/polymers-13-00274-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/698acb74fd92/polymers-13-00274-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/3edfd5e7d31b/polymers-13-00274-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/8544bb29a967/polymers-13-00274-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/8f113b9f72a4/polymers-13-00274-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/6cbb647d6fc0/polymers-13-00274-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/c1f0a1c4c494/polymers-13-00274-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/d42687013254/polymers-13-00274-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/ddf4b317fa21/polymers-13-00274-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/7a0ed299d6a4/polymers-13-00274-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/1cefec88e259/polymers-13-00274-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/aed6b5ff378a/polymers-13-00274-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/4a23af5654b7/polymers-13-00274-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/9bad4c40eacc/polymers-13-00274-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/4724e33b9da2/polymers-13-00274-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/698acb74fd92/polymers-13-00274-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/3edfd5e7d31b/polymers-13-00274-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/8544bb29a967/polymers-13-00274-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f51c/7830891/8f113b9f72a4/polymers-13-00274-g014.jpg

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