Nechipurenko Sergey V, Bobrova Valeriya V, Kasperovich Andrey V, Yermaganbetov Mubarak Ye, Yefremov Sergey A, Kaiaidarova Aigerim K, Makhayeva Danelya N, Yermukhambetova Bayana B, Mun Grigoriy A, Irmukhametova Galiya S
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan.
National Engineering Academy of the Republic of Kazakhstan, Almaty 050010, Kazakhstan.
Materials (Basel). 2024 Dec 30;18(1):114. doi: 10.3390/ma18010114.
This study examined the effect of partially replacing semi-reinforcing carbon black grade N550 (up to 10 pts. wt.) and fully replacing industrial chalk with natural shungite mineral in industrial formulations of elastomer compositions intended for manufacturing various rubber technical products. It has been shown that due to the high content of carbon and silicon components in the composition of shungite mineral micropowders, their use as a filler in elastomer formulations significantly improves the physical and mechanical properties of rubber technical products (RTPs) manufactured using such compositions. It was determined that the use of SM as a partial replacement for carbon black in rubbers intended for molded rubber technical products contributes to a reduction in Mooney viscosity (up to 26.8%) and optimal vulcanization time (up to 23.7%), achieving rubbers with the required set of physical-mechanical properties and with an enhancing sealing capability (up to 19.7%). It has been established that the use of shungite mineral micropowders as a complete replacement for industrial chalk increases the strength of rubber products (RTPs) by up to 18.5% and enhances their resistance to liquid aggressive environments.
本研究考察了在用于制造各种橡胶技术产品的弹性体组合物工业配方中,部分替代半补强炭黑N550级(最高10份重量)以及用天然硅碳石矿物完全替代工业白垩的效果。结果表明,由于硅碳石矿物微粉的成分中碳和硅组分含量高,将其用作弹性体配方中的填料可显著改善使用此类组合物制造的橡胶技术产品(RTP)的物理和机械性能。已确定,在用于模压橡胶技术产品的橡胶中,使用硅碳石矿物微粉部分替代炭黑有助于降低门尼粘度(高达26.8%)和优化硫化时间(高达23.7%),从而获得具有所需物理机械性能组合且密封能力增强(高达19.7%)的橡胶。已证实,使用硅碳石矿物微粉完全替代工业白垩可使橡胶产品(RTP)的强度提高高达18.5%,并增强其对液体侵蚀性环境的耐受性。