UHMWPE / nanodiamond nanocomposites for orthopaedic applications: A novel sandwich configuration based approach.

Ultra high molecular weight polyethylene (UHMWPE) remains a primary choice of material for load bearing applications in total joint arthroplasty. Superior mechanical properties and wear resistance are unique to its performance. However, the addition of nanomaterials has improved its properties significantly. In the present study, a novel sandwich configuration has been considered to achieve unique surface and bulk properties specific to these sandwich composites. UHMWPE was reinforced at various loadings of 0.1, 0.3, 0.5, and 0.7 wt. % by surface modified Nano-diamond (ND). It is observed that the young's modulus, yield stress, fracture stress and toughness of UHMWPE were improved by 15, 31, 30, and 49.6% respectively at the optimum loading of 0.5 wt. % ND filler. The % of elongations and impact strength showed best results at 0.3 wt. % ND. Sandwich nanocomposites were prepared with the optimum loading of 0.3 & 0.5 wt. % ND and assessed for their properties and behaviour. The sectional hardness of sandwich nanocomposites revealed the cross-sectional variation of properties of the material. The reasons for diminution of the mechanical properties of nanocomposites and sandwich nanocomposites were also ascertained by rheological studies. The vibration response, damping behaviour, water contact angle and density of the composites which influence the longevity of the implant material were also assessed. The sandwich composite (PE 0.3ND - PE - PE 0.3ND) has shown better performance in all respect as compare to SW1 and SW3 composite due to good intermingling between the adjacent layers. It is concluded that the existence of ND improved the surface properties and mechanical properties of UHMWPE. However, sandwich nanocomposites have shown better properties unique unto itself.