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芘-硼二吡咯取代的新型水溶性环三磷腈：合成、表征及光物理性质

Pyrene-BODIPY-substituted novel water-soluble cyclotriphosphazenes: synthesis, characterization, and photophysical properties.

作者信息

Çetİndere Seda, YeŞİlot Serkan, KiliÇ Adem

机构信息

Department of Chemistry, Gebze Technical University, Gebze, Kocaeli Turkey.

Institute of Inorganic Chemistry I, Ulm University, Ulm Germany.

出版信息

Turk J Chem. 2020 Feb 11;44(1):1-14. doi: 10.3906/kim-1907-40. eCollection 2020.

DOI:10.3906/kim-1907-40
PMID:33488139
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7751814/
Abstract

In the present work, pyrene-boron-dipyrromethene (BODIPY)-substituted novel water-soluble cyclotriphosphazene derivatives (6 and 7) were synthesized by click reactions between a cyclotriphosphazene derivative with a hydrophilic glycol side group (2) and BODIPYs (4 and 5). All of the new compounds (2, 6, and 7) were characterized by Fourier-transform infrared and nuclear magnetic resonance spectroscopy, as well as mass spectrometry and elemental analysis. The photophysical properties of the BODIPY-substituted cyclotriphosphazenes (6 and 7) were investigated by UV-Vis and fluorescence emission spectroscopy in water and water/solvent mixtures. It was found that the target compounds were soluble in water and could be potential candidates as water-soluble fluorescent dyes for the desired applications.

摘要

在本工作中，通过带有亲水性二醇侧基的环三磷腈衍生物（2）与硼二吡咯亚甲基（BODIPY）（4和5）之间的点击反应，合成了芘基硼二吡咯亚甲基（BODIPY）取代的新型水溶性环三磷腈衍生物（6和7）。所有新化合物（2、6和7）均通过傅里叶变换红外光谱、核磁共振光谱以及质谱和元素分析进行了表征。通过紫外可见光谱和荧光发射光谱研究了BODIPY取代的环三磷腈（6和7）在水和水/溶剂混合物中的光物理性质。发现目标化合物可溶于水，并且有可能成为用于所需应用的水溶性荧光染料的潜在候选物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c597/7751814/a341ca009b82/turkjchem-44-1-fig014.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c597/7751814/b64a63c92c3d/turkjchem-44-1-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c597/7751814/4443289351d8/turkjchem-44-1-fig004.jpg
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