• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（3-吗啉-4-基丙氧基）取代的钴、锰酞菁的取代基位置、金属类型对其电化学性质的影响及合成

Synthesis and effect of substituent position, metal type on the electrochemical properties of (3-morpholin-4-ylpropoxy) groups substituted cobalt, manganese phthalocyanines.

作者信息

BiyiklioĞlu Zekeriya, BaŞ Hüseyin

机构信息

Department of Chemistry, Karadeniz Technical University, Trabzon turkey.

出版信息

Turk J Chem. 2020 Jun 1;44(3):687-694. doi: 10.3906/kim-2001-54. eCollection 2020.

DOI:10.3906/kim-2001-54
PMID:33488186
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7671230/
Abstract

In this work, 4-(3-morpholin-4-ylpropoxy)phthalonitrile 2, 3-(3-morpholin-4-ylpropoxy)phthalonitrile 3, Co(II)Pc and Mn(III)Pcs containing (3-morpholin-4-ylpropoxy) groups at peripheral and nonperipheral positions were synthesized. Phthalonitrile derivatives (2 and 3), Co(II)Pc and Mn(III)Pcs (2a, 2b, 3a, 3b) were characterized by using FT-IR, NMR (only for 2 and 3), mass and UV-Vis (except 2 and 3) spectral data techniques. Also, electrochemistry of (3-morpholin-4-ylpropoxy) group substituted Co(II)Pc and Mn(III)Pcs were inspected by using cyclic voltammetry. Electrochemical studies show that (3-morpholin-4-ylpropoxy) group substituted Co(II)Pc and Mn(III)Pcs electropolymerized on the Pt working electrode.

摘要

在本工作中，合成了4-(3-吗啉-4-基丙氧基)邻苯二甲腈2、3-(3-吗啉-4-基丙氧基)邻苯二甲腈3、在周边和非周边位置含有(3-吗啉-4-基丙氧基)基团的Co(II)酞菁和Mn(III)酞菁。通过傅里叶变换红外光谱(FT-IR)、核磁共振(NMR，仅用于2和3)、质谱以及紫外-可见光谱(UV-Vis，2和3除外)数据技术对邻苯二甲腈衍生物(2和3)、Co(II)酞菁和Mn(III)酞菁(2a、2b、3a、3b)进行了表征。此外，采用循环伏安法研究了(3-吗啉-4-基丙氧基)基团取代的Co(II)酞菁和Mn(III)酞菁的电化学性质。电化学研究表明，(3-吗啉-4-基丙氧基)基团取代的Co(II)酞菁和Mn(III)酞菁在铂工作电极上发生了电聚合。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/a1a62d6705b1/turkjchem-44-687-fig007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/1420c824335d/turkjchem-44-687-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/0d3495db56b7/turkjchem-44-687-fig002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/ba5f6be99528/turkjchem-44-687-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/4c9236f70feb/turkjchem-44-687-fig004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/1df50f06d78f/turkjchem-44-687-fig005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/2339423c3168/turkjchem-44-687-fig006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/a1a62d6705b1/turkjchem-44-687-fig007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/1420c824335d/turkjchem-44-687-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/0d3495db56b7/turkjchem-44-687-fig002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/ba5f6be99528/turkjchem-44-687-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/4c9236f70feb/turkjchem-44-687-fig004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/1df50f06d78f/turkjchem-44-687-fig005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/2339423c3168/turkjchem-44-687-fig006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a2e/7671230/a1a62d6705b1/turkjchem-44-687-fig007.jpg

相似文献

1
Synthesis and effect of substituent position, metal type on the electrochemical properties of (3-morpholin-4-ylpropoxy) groups substituted cobalt, manganese phthalocyanines.（3-吗啉-4-基丙氧基）取代的钴、锰酞菁的取代基位置、金属类型对其电化学性质的影响及合成
Turk J Chem. 2020 Jun 1;44(3):687-694. doi: 10.3906/kim-2001-54. eCollection 2020.
2
Synthesis and electrochemical properties of copper(II), manganese(III) phthalocyanines bearing chalcone groups at peripheral or nonperipheral positions.在周边或非周边位置带有查尔酮基团的铜（II）、锰（III）酞菁的合成及电化学性质
Turk J Chem. 2020 Dec 16;44(6):1549-1555. doi: 10.3906/kim-2006-21. eCollection 2020.
3
An effect of the substituent position and metal type on the electropolymerization properties of chalcone substituted metallophthalocyanines.取代基位置和金属类型对查耳酮取代金属酞菁电聚合性能的影响。
Dalton Trans. 2015 Dec 28;44(48):20859-66. doi: 10.1039/c5dt03789a. Epub 2015 Nov 9.
4
α- and β-Substituted Metal-Free Phthalocyanines: Synthesis, Photophysical and Electrochemical Properties.α-和β-取代的无金属酞菁：合成、光物理和电化学性质。
Molecules. 2020 Jan 16;25(2):363. doi: 10.3390/molecules25020363.
5
Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry.非周边四-[5-(二乙氨基)-2-甲酰基苯氧基]取代金属酞菁的合成及其电化学
Turk J Chem. 2021 Feb 17;45(1):17-25. doi: 10.3906/kim-2007-47. eCollection 2021.
6
The peripheral and non-peripheral 2H-benzotriazole substituted phthalocyanines: Synthesis, characterization, photophysical and photochemical studies of zinc derivatives.外周和非外周2H-苯并三唑取代的酞菁：锌衍生物的合成、表征、光物理和光化学研究
Spectrochim Acta A Mol Biomol Spectrosc. 2019 Jun 15;217:128-140. doi: 10.1016/j.saa.2019.01.095. Epub 2019 Mar 22.
7
Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-phthalocyanines: synthesis, characterization, and investigation of their electrochemical, photochemical and computational properties.新型非周边八-3-羟丙硫基取代金属酞菁：合成、表征及其电化学、光化学和计算性质研究
Turk J Chem. 2021 Feb 17;45(1):143-156. doi: 10.3906/kim-2008-48. eCollection 2021.
8
Isostructural dinuclear phenoxo-/acetato-bridged manganese(II), cobalt(II), and zinc(II) complexes with labile sites: kinetics of transesterification of 2-hydroxypropyl-p-nitrophenylphosphate.具有结构同型的双核邻苯氧根/乙酰氧桥联的锰(II)、钴(II)和锌(II)配合物，具有不稳定的配位位置：2-羟丙基对硝基苯膦酸酯的酯交换反应动力学。
Inorg Chem. 2012 May 21;51(10):5539-53. doi: 10.1021/ic201971t. Epub 2012 Apr 26.
9
The synthesis and characterization of nonperipherally tetra terminal alkynyl substituted phthalocyanines and glycoconjugation via the click reaction.非周边四末端炔基取代酞菁的合成与表征以及通过点击反应进行的糖缀合。
Dalton Trans. 2014 Jun 21;43(23):8654-63. doi: 10.1039/c4dt00238e.
10
Effect of Direct Alkyne Substitution on the Photophysical Properties of Two Novel Octasubstituted Zinc Phthalocyanines.直接炔基取代对两种新型八取代锌酞菁光物理性质的影响。
ChemistryOpen. 2024 Jul;13(7):e202300295. doi: 10.1002/open.202300295. Epub 2024 Jan 26.

引用本文的文献

1
Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry.非周边四-[5-(二乙氨基)-2-甲酰基苯氧基]取代金属酞菁的合成及其电化学
Turk J Chem. 2021 Feb 17;45(1):17-25. doi: 10.3906/kim-2007-47. eCollection 2021.

本文引用的文献

1
A Spin-Active, Electrochromic, Solvent-Free Molecular Liquid Based on Double-Decker Lutetium Phthalocyanine Bearing Long Branched Alkyl Chains.基于带有长支链烷基链的双层镥酞菁的自旋活性、电致变色、无溶剂分子液体。
Chem Asian J. 2018 Apr 4;13(7):770-774. doi: 10.1002/asia.201800175. Epub 2018 Feb 27.
2
Zinc(II) phthalocyanine fused in peripheral positions octa-substituted with alkyl linked carbazole: Synthesis, electropolymerization and its electro-optic and biosensor applications.锌(II)酞菁在周边位置与连接咔唑的烷基八取代融合：合成、电聚合及其光电和生物传感器应用。
Biosens Bioelectron. 2017 Dec 15;98:202-209. doi: 10.1016/j.bios.2017.06.028. Epub 2017 Jun 19.
3
Mono- and tetra-substituted zinc(II) phthalocyanines containing morpholinyl moieties: Synthesis, antifungal photodynamic activities, and structure-activity relationships.
含有吗啉基部分的单核和四取代锌(II)酞菁：合成、抗真菌光动力活性及构效关系。
Eur J Med Chem. 2016 May 23;114:380-9. doi: 10.1016/j.ejmech.2016.02.066. Epub 2016 Mar 3.
4
An effect of the substituent position and metal type on the electropolymerization properties of chalcone substituted metallophthalocyanines.取代基位置和金属类型对查耳酮取代金属酞菁电聚合性能的影响。
Dalton Trans. 2015 Dec 28;44(48):20859-66. doi: 10.1039/c5dt03789a. Epub 2015 Nov 9.
5
Electrocatalytic activity of cobalt phthalocyanine stabilized by different matrixes.不同基质稳定的钴酞菁的电催化活性。
Anal Bioanal Chem. 2002 Nov;374(5):891-7. doi: 10.1007/s00216-002-1562-x. Epub 2002 Oct 18.