• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于噻吩并[3,2 - ]噻吩的用于电致变色应用的铁（II）金属超分子聚合物。

Iron (II) Metallo-Supramolecular Polymers Based on Thieno[3,2-]thiophene for Electrochromic Applications.

作者信息

Chernyshev Andrei, Acharya Udit, Pfleger Jiří, Trhlíková Olga, Zedník Jiří, Vohlídal Jiří

机构信息

Faculty of Science, Department of Physical and Macromolecular Chemistry, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic.

Institute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovského nám. 2, 162 06 Prague 6, Czech Republic.

出版信息

Polymers (Basel). 2021 Jan 23;13(3):362. doi: 10.3390/polym13030362.

DOI:10.3390/polym13030362
PMID:33498749
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7865520/
Abstract

Four new bis() unimers with different linkers between the thieno[3,2-]thiophene-2,5-diyl central unit and terpyridine-4'-yl () end-groups: no linker (), ethynediyl (), 1,4-phenylene () and 2,2'-bithophene-5,5'-diyl () are prepared, characterized, and assembled with Fe ions to metallo-supramolecular polymers (Fe-MSPs). The Fe-MSP films prepared by spin-casting on Indium Tin Oxide (ITO) glass are characterized by atomic force microscope (AFM) microscopy, cyclic voltammetry, and UV/vis spectroscopy and studied for their electrochromism and effect of the unimer structure on their electrochromic performance. Of the studied MSPs, shows the highest optical contrast as well as coloration efficiency (CE = 641 cm C) and the fastest optical response. This makes it an excellent candidate for possible use in electrochromic devices.

摘要

制备了四种新型双（）单体，它们在噻吩并[3,2 - ]噻吩 - 2,5 - 二基中心单元和三联吡啶 - 4'- 基（）端基之间具有不同的连接基团：无连接基团（）、乙炔二基（）、1,4 - 亚苯基（）和2,2'- 联噻吩 - 5,5'- 二基（），对其进行了表征，并与铁离子组装成金属超分子聚合物（Fe - MSPs）。通过旋涂在氧化铟锡（ITO）玻璃上制备的Fe - MSP薄膜，用原子力显微镜（AFM）显微镜、循环伏安法和紫外/可见光谱进行了表征，并研究了它们的电致变色性能以及单体结构对其电致变色性能的影响。在所研究的MSPs中，显示出最高的光学对比度以及着色效率（CE = 641 cm C）和最快的光学响应。这使其成为可能用于电致变色器件的极佳候选材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/45f5616ceec3/polymers-13-00362-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/19f4d8503fd8/polymers-13-00362-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/9349459a1037/polymers-13-00362-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/46f8deadfb60/polymers-13-00362-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/027e4c4b6bb8/polymers-13-00362-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/e7331693dd07/polymers-13-00362-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/95fdd6bcc5c4/polymers-13-00362-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/0c75f545a496/polymers-13-00362-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/30a0ebe7c802/polymers-13-00362-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/941b3e053a14/polymers-13-00362-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/b1e3753d1b19/polymers-13-00362-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/45f5616ceec3/polymers-13-00362-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/19f4d8503fd8/polymers-13-00362-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/9349459a1037/polymers-13-00362-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/46f8deadfb60/polymers-13-00362-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/027e4c4b6bb8/polymers-13-00362-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/e7331693dd07/polymers-13-00362-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/95fdd6bcc5c4/polymers-13-00362-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/0c75f545a496/polymers-13-00362-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/30a0ebe7c802/polymers-13-00362-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/941b3e053a14/polymers-13-00362-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/b1e3753d1b19/polymers-13-00362-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69e8/7865520/45f5616ceec3/polymers-13-00362-g008.jpg

相似文献

1
Iron (II) Metallo-Supramolecular Polymers Based on Thieno[3,2-]thiophene for Electrochromic Applications.基于噻吩并[3,2 - ]噻吩的用于电致变色应用的铁（II）金属超分子聚合物。
Polymers (Basel). 2021 Jan 23;13(3):362. doi: 10.3390/polym13030362.
2
Bis(terpyridine) Iron(II) Functionalized Vertically-Oriented Nanostructured Silica Films: Toward Electrochromic Materials.双（三联吡啶）铁（II）功能化垂直取向纳米结构二氧化硅薄膜：用于电致变色材料
Front Chem. 2020 Sep 15;8:830. doi: 10.3389/fchem.2020.00830. eCollection 2020.
3
Constructing Alternated Heterobimetallic [Fe(II)/Os(II)] Supramolecular Polymers with Diverse Solubility for Facile Fabrication of Voltage-Tunable Multicolor Electrochromic Devices.构建具有不同溶解性的交替异双金属[铁（II）/锇（II）]超分子聚合物，用于便捷制备电压可调多色电致变色器件。
ACS Appl Mater Interfaces. 2020 Mar 25;12(12):14376-14385. doi: 10.1021/acsami.9b21966. Epub 2020 Mar 16.
4
A Thiophene-Containing Conductive Metallopolymer Using an Fe(II) Bis(terpyridine) Core for Electrochromic Materials.含噻吩的导电金属聚合物，以 Fe(II) 双(三联吡啶)为核心，用于电致变色材料。
ACS Appl Mater Interfaces. 2016 Dec 21;8(50):34568-34580. doi: 10.1021/acsami.6b11657. Epub 2016 Dec 12.
5
Novel Metallo-Supramolecular Polymers with 1-Thioxophosphole Main-Chain Units and Remarkable Photoinduced Changes in Their Resonance Raman Spectra.具有1-硫代磷杂环戊二烯主链单元的新型金属超分子聚合物及其共振拉曼光谱中显著的光致变化
Polymers (Basel). 2022 Nov 30;14(23):5207. doi: 10.3390/polym14235207.
6
Transparent Supercapacitor Display with Redox-Active Metallo-Supramolecular Polymer Films.具有氧化还原活性金属超分子聚合物薄膜的透明超级电容器显示器
ACS Appl Mater Interfaces. 2020 Apr 8;12(14):16342-16349. doi: 10.1021/acsami.9b23123. Epub 2020 Mar 27.
7
Mechanistic Insights into Anion-Induced Electrochromism of Ru(II)-Based Metallo-Supramolecular Polymer.基于钌（II）的金属超分子聚合物中阴离子诱导电致变色的机理研究
Polymers (Basel). 2023 Dec 18;15(24):4735. doi: 10.3390/polym15244735.
8
Alcohol-soluble bis(tpy)thiophenes: new building units for constitutional dynamic conjugated polyelectrolytes.醇溶性双（三联吡啶）噻吩：用于构建动态共轭聚电解质的新型结构单元。
Phys Chem Chem Phys. 2015 May 28;17(20):13743-56. doi: 10.1039/c5cp01000d.
9
Three-dimensional Fe(II)-based metallo-supramolecular polymers with electrochromic properties of quick switching, large contrast, and high coloration efficiency.具有快速切换、高对比度和高着色效率等电致变色特性的三维铁（II）基金属超分子聚合物。
ACS Appl Mater Interfaces. 2014 Jun 25;6(12):9118-25. doi: 10.1021/am5010859. Epub 2014 Jun 3.
10
Electrochromic properties of a metallo-supramolecular polymer derived from tetra(2-pyridyl-1,4-pyrazine) ligands integrated in thin multilayer films.基于集成在多层薄膜中的四（2-吡啶基-1,4-吡嗪）配体的金属超分子聚合物的电致变色性质。
Langmuir. 2012 Feb 14;28(6):3332-7. doi: 10.1021/la204280e. Epub 2012 Feb 2.

引用本文的文献

1
Synapse-Mimicking Memristors Based on 3,6-Di()-9-Phenylcarbazole Unimer and Its Copolymer with Cobalt(II) Ions.基于3,6-二（）-9-苯基咔唑单体及其与钴（II）离子共聚物的类突触忆阻器
Polymers (Basel). 2024 Feb 17;16(4):542. doi: 10.3390/polym16040542.
2
Novel Metallo-Supramolecular Polymers with 1-Thioxophosphole Main-Chain Units and Remarkable Photoinduced Changes in Their Resonance Raman Spectra.具有1-硫代磷杂环戊二烯主链单元的新型金属超分子聚合物及其共振拉曼光谱中显著的光致变化
Polymers (Basel). 2022 Nov 30;14(23):5207. doi: 10.3390/polym14235207.

本文引用的文献

1
Dual-Branched Dense Hexagonal Fe(II)-Based Coordination Nanosheets with Red-to-Colorless Electrochromism and Durable Device Fabrication.具有从红色到无色电致变色及耐用器件制造性能的双支链致密六边形铁（II）基配位纳米片
ACS Appl Mater Interfaces. 2020 Jul 15;12(28):31896-31903. doi: 10.1021/acsami.0c05921. Epub 2020 Jun 30.
2
Multi-color electrochromism from coordination nanosheets based on a terpyridine-Fe(ii) complex.基于三联吡啶-Fe(ii) 配合物的配位纳米片的多色电致变色。
Dalton Trans. 2019 Oct 14;48(40):15121-15126. doi: 10.1039/c9dt02980j.
3
Electrochromic Sensors Based on Conducting Polymers, Metal Oxides, and Coordination Complexes.
基于导电聚合物、金属氧化物和配位配合物的电致变色传感器。
Crit Rev Anal Chem. 2019;49(3):195-208. doi: 10.1080/10408347.2018.1499009. Epub 2018 Oct 4.
4
Ligand Impact on Monolayer Electrochromic Material Properties.配体对单层电致变色材料性能的影响。
ACS Appl Mater Interfaces. 2018 Oct 17;10(41):35334-35343. doi: 10.1021/acsami.8b10666. Epub 2018 Oct 3.
5
Green-to-Red Electrochromic Fe(II) Metallo-Supramolecular Polyelectrolytes Self-Assembled from Fluorescent 2,6-Bis(2-pyridyl)pyrimidine Bithiophene.由荧光2,6-双(2-吡啶基)嘧啶联噻吩自组装而成的绿色到红色电致变色亚铁(II)金属超分子聚电解质
Inorg Chem. 2017 Feb 6;56(3):1418-1432. doi: 10.1021/acs.inorgchem.6b02496. Epub 2017 Jan 20.
6
A Thiophene-Containing Conductive Metallopolymer Using an Fe(II) Bis(terpyridine) Core for Electrochromic Materials.含噻吩的导电金属聚合物，以 Fe(II) 双(三联吡啶)为核心，用于电致变色材料。
ACS Appl Mater Interfaces. 2016 Dec 21;8(50):34568-34580. doi: 10.1021/acsami.6b11657. Epub 2016 Dec 12.
7
Synthesis and characterization of metallo-supramolecular polymers.金属超分子聚合物的合成与表征。
Chem Soc Rev. 2016 Oct 7;45(19):5311-57. doi: 10.1039/c6cs00182c. Epub 2016 May 24.
8
Alcohol- and water-soluble bis(tpy)quaterthiophenes with phosphonium side groups: new conjugated units for metallo-supramolecular polymers.带有鏻侧基的醇溶性和水溶性双（三联吡啶）四硫代苯：用于金属超分子聚合物的新型共轭单元
Dalton Trans. 2016 Jan 21;45(3):1208-24. doi: 10.1039/c5dt04133c.
9
Alcohol-soluble bis(tpy)thiophenes: new building units for constitutional dynamic conjugated polyelectrolytes.醇溶性双（三联吡啶）噻吩：用于构建动态共轭聚电解质的新型结构单元。
Phys Chem Chem Phys. 2015 May 28;17(20):13743-56. doi: 10.1039/c5cp01000d.
10
Highly emissive, solution-processable and dynamic Eu(III)-containing coordination polymers.高发射性、可溶液加工且具有动态特性的含铕（III）配位聚合物。
Chem Commun (Camb). 2015 May 21;51(41):8656-9. doi: 10.1039/c5cc01793a.