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平行于基底堆叠的Mg(OH)层状薄膜的电化学生长及其向(111)取向纳米多孔MgO薄膜的热转化

Electrochemical Growth of Mg(OH) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films.

作者信息

Shinagawa Tsutomu, Chigane Masaya, Izaki Masanobu

机构信息

Electronic Materials Research Division, Morinomiya Center, Osaka Research Institute of Industrial Science and Technology (ORIST), Osaka 536-8553, Japan.

Graduate School of Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan.

出版信息

ACS Omega. 2021 Jan 11;6(3):2312-2317. doi: 10.1021/acsomega.0c05619. eCollection 2021 Jan 26.

DOI:10.1021/acsomega.0c05619
PMID:33521469
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7841930/
Abstract

Stacking layered metal hydroxide films parallel to a substrate is challenging. Here, we demonstrate a simple and rapid electrodeposition method for stacking magnesium hydroxide layered films. Room-temperature cathodic electrolysis (40 mA cm) in a Mg(NO) aqueous solution induces the deposition of ⟨001⟩-oriented Mg(OH) layered films stacked parallel to the substrate at the deposition rate of ∼2 μm min. The obtained Mg(OH) layered films undergo an overall oriented transformation by heat treatment to form ⟨111⟩-oriented nanoporous MgO films.

摘要

将层状金属氢氧化物薄膜平行于基底堆叠具有挑战性。在此，我们展示了一种用于堆叠氢氧化镁层状薄膜的简单快速的电沉积方法。在硝酸镁水溶液中进行室温阴极电解（40 mA/cm²）会诱导出与基底平行堆叠的〈001〉取向的氢氧化镁层状薄膜的沉积，沉积速率约为2 μm/min。所获得的氢氧化镁层状薄膜通过热处理经历整体取向转变，形成〈111〉取向的纳米多孔氧化镁薄膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/2fd5b925c4d2/ao0c05619_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/1f6a32e5ba17/ao0c05619_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/896df213ce77/ao0c05619_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/8046888445cf/ao0c05619_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/ed541de24be7/ao0c05619_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/149f3bc49a14/ao0c05619_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/eb71ee9a698b/ao0c05619_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/2fd5b925c4d2/ao0c05619_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/1f6a32e5ba17/ao0c05619_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/896df213ce77/ao0c05619_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/8046888445cf/ao0c05619_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/ed541de24be7/ao0c05619_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/149f3bc49a14/ao0c05619_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/eb71ee9a698b/ao0c05619_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da46/7841930/2fd5b925c4d2/ao0c05619_0007.jpg

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