Liu Shijie, Cui Suping, Guo Hongxia, Wang Yali, Zheng Yan
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China.
Materials (Basel). 2021 Feb 10;14(4):842. doi: 10.3390/ma14040842.
In order to obtain low-cost and excellent adsorption materials, this paper used calcium acetate and water glass as raw materials to synthesis hydrated calcium silicate gel by precipitation method. The performance and structure of hydrated calcium silicate gel were systematically studied by X-ray photoelectron spectroscopy, fourier transform infrared spectroscopy, specific surface area analyzer and scanning electron microscope. Studies have shown that, non-crystal hydrated calcium silicate gel (CSH) were successfully prepared, and the removal rate of lead ion using CSH reached more than 90%. The adsorption process is consistent with the pseudo-second-order kinetic model and Langmuir adsorption isotherm model, and the limit adsorption capacity reaches 263.17 mg·g. The acid treatment experiment proved that the adsorption capacity of lead ion using CSH was satisfactory, and the adsorption rate remained at >60% after 5 cycles. The research may provide a low-cost, high-efficiency and high stability adsorbent.
为了获得低成本且性能优异的吸附材料,本文以醋酸钙和水玻璃为原料,采用沉淀法合成水合硅酸钙凝胶。通过X射线光电子能谱、傅里叶变换红外光谱、比表面积分析仪和扫描电子显微镜对水合硅酸钙凝胶的性能和结构进行了系统研究。研究表明,成功制备了非晶态水合硅酸钙凝胶(CSH),CSH对铅离子的去除率达到90%以上。吸附过程符合准二级动力学模型和朗缪尔吸附等温线模型,极限吸附容量达到263.17 mg·g 。酸处理实验证明,CSH对铅离子的吸附性能良好,5次循环后吸附率仍保持在>60%。该研究可为低成本、高效、高稳定性吸附剂的开发提供参考。