Shubha J Pranesh, Adil Syed F, Khan Mujeeb, Hatshan Mohammad R, Khan Aslam
Department of Chemistry, Don Bosco Institute of Technology, Mysore Road, Bangalore 560 074, India.
Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia.
ACS Omega. 2021 Jan 29;6(5):3866-3874. doi: 10.1021/acsomega.0c05670. eCollection 2021 Feb 9.
The ZnO-based ternary heterostructure ZnO/EuO/NiO nanoparticles are synthesized using waste curd as fuel by a simple one-pot combustion method. The as-synthesized heterostructure is characterized by using various spectroscopic and microscopic techniques including X-ray diffraction, UV-vis, FTIR, SEM, and TEM analyses. The photocatalytic activity of the ternary nanocomposite was tested for the photodegradation of methylene blue (MB) under solar light irradiation. The results have revealed that the ternary ZnO/EuO/NiO photocatalyst exhibits excellent performance toward the photocatalytic degradation of the studied dye. Optimization studies revealed that the synthesized heterostructure exhibited a pH-dependent photocatalytic activity, and better results are obtained for specific concentrations of dye and catalysts. Among the different light sources employed during the study, the catalyst was found to possess the best degradation efficiency in visible light.
采用简易的一锅燃烧法,以废弃凝乳为燃料合成了基于氧化锌的三元异质结构氧化锌/氧化铕/氧化镍纳米颗粒。通过包括X射线衍射、紫外可见光谱、傅里叶变换红外光谱、扫描电子显微镜和透射电子显微镜分析在内的各种光谱和显微镜技术对合成的异质结构进行了表征。测试了三元纳米复合材料在太阳光照射下对亚甲基蓝(MB)的光降解光催化活性。结果表明,三元氧化锌/氧化铕/氧化镍光催化剂对所研究染料的光催化降解表现出优异的性能。优化研究表明,合成的异质结构表现出pH依赖性光催化活性,对于特定浓度的染料和催化剂可获得更好的结果。在研究过程中使用的不同光源中,发现该催化剂在可见光下具有最佳的降解效率。