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MXenes:合成、光学性质及其在超快光子学中的应用。

MXenes: Synthesis, Optical Properties, and Applications in Ultrafast Photonics.

机构信息

BUAA-CCMU Advanced Innovation Center for Big Data-Based Precision Medicine, School of Medicine and Engineering, Beihang University, Beijing, 100191, China.

Key Laboratory of Big Data-Based Precision Medicine, Ministry of Industry and Information Technology, Interdisciplinary Innovation Institute of Medicine and Engineering, Beihang University, Beijing, 100191, China.

出版信息

Small. 2021 Mar;17(11):e2006054. doi: 10.1002/smll.202006054. Epub 2021 Feb 16.

Abstract

Recently, 2D materials are in great demand for various applications such as optical devices, supercapacitors, sensors, and biomedicine. MXenes as a kind of novel 2D material have attracted considerable research interest due to their outstanding mechanical, thermal, electrical, and optical properties. Especially, the excellent nonlinear optical response enables them to be potential candidates for the applications in ultrafast photonics. Here, a review of MXenes synthesis, optical properties, and applications in ultrafast lasers is presented. First, aqueous acid etching and chemical vapor deposition methods for preparing MXenes are introduced, in which the storage stability and challenges of the existing synthesis techniques are also discussed. Then, the optical properties of MXenes are discussed specifically, including plasmonic properties, optical detection, photothermal effects, and ultrafast dynamics. Furthermore, the typical ultrafast pulsed lasers enabled by MXene-based saturable absorbers operated at different wavelength regions are summarized. Finally, a summary and outlook on the development of MXenes is presented in the perspectives section.

摘要

近年来,二维(2D)材料在光学器件、超级电容器、传感器和生物医学等各个领域的应用中需求巨大。MXenes 作为一种新型 2D 材料,由于其出色的机械、热学、电学和光学性能而引起了相当大的研究兴趣。特别是,其优异的非线性光学响应使它们成为超快光子学应用的潜在候选材料。本文综述了 MXenes 的合成、光学性质及其在超快激光器中的应用。首先介绍了用于制备 MXenes 的水相酸刻蚀法和化学气相沉积法,并讨论了其存储稳定性和现有合成技术的挑战。然后详细讨论了 MXenes 的光学性质,包括等离子体特性、光学检测、光热效应和超快动力学。此外,还总结了基于 MXene 的可饱和吸收体在不同波长区域工作的典型超快脉冲激光器。最后,在展望部分总结和展望了 MXenes 的发展。

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