Titanium dioxide (TiO) nanoparticles reinforced polyvinyl formal (PVF) nanocomposites as chemiresistive gas sensor for sulfur dioxide (SO) monitoring.

The present work reports the preparation of polyvinyl formal (PVF)/Titanium dioxide (TiO) nanocomposite films using a solution casting method followed by the characterization of the synthesized PVF/TiO nanocomposite films using various analytical techniques namely FTIR, XRD, UV-vis, SEM and TGA analysis. The results obtained from different analyses confirmed that the TiO NPs was fine dispersed within the PVF matrix and there exists well compatibility among the polymer matrix and the nanofiller. The pristine TiO NPs based fabricated chemiresistive sensor exhibits the maximum sensitivity of 50.25% at 370 °C where as PVF/TiO nanocomposite sensor showed the enhanced sensitivity of 83.75% at a relatively low operating temperature of 150 °C towards 600 ppm sulfur dioxide (SO) gas. The 25 wt% PVF/TiO nanocomposite film sensor exhibited good sensitivity (∼83.75%), selectivity, rapid response time (66 s)/recovery time (107 s), and long-term stability of 60 days for SO gas detection. The fabricated PVF/TiO nanocomposite film sensors in our work possesses the advantages of low power consumption, cost-effective, and distinguished sensing abilities for SO detection makes it possible for potential applications. Thus, the fabricated chemiresistive sensors based on TiO NPs reinforced PVF nanocomposites films are evaluated and experimental results to show an excellent behavior towards SO gas detection for industrial processes control and environmental monitoring applications.