Hu Zhi-Yuan, Luo Jun, Lu Zhang-Ying, Wang Zhuo, Tan Pi-Qiang, Lou Di-Ming
School of Automotive Studies, Tongji University, Shanghai 201804, China.
ACS Omega. 2021 Feb 10;6(7):5046-5055. doi: 10.1021/acsomega.0c06254. eCollection 2021 Feb 23.
Used cooking oil (UCO) biodiesel may be one of the most potential alternative fuels in China to lower the dependency on crude oil for transportation. An experimental study has been conducted to assess the interactions between biodiesel produced from UCO in Shanghai and elastomer materials on high-speed marine diesel engines by immersing elastomer materials into conventional fossil diesel, 5, 10, and 20%, of a volumetric blending ratio of UCO biodiesel and pure UCO biodiesel. The test duration is 168 h at different temperatures of 25, 50, and 70 °C. Meanwhile, the effects of the mixing ratio of UCO biodiesel and the immersion temperature on the compatibility of elastomer materials with UCO biodiesel were analyzed. The results revealed that elastomer materials such as nitrile butadiene rubber (NBR), ethylene propylene diene monomer (EPDM), fluororubber (FKM), and silicone rubber (SR) exposed to biodiesel blends would reveal worse but acceptable changes than those exposed to petroleum diesel, including the slight increase of mass and volume and decline of tensile strength and hardness. FKM, NBR, and SR represented better compatibility with pure UCO biodiesel than diesel, and EPDM showed worse compatibility with UCO biodiesel as the blend ratio rises. In general, the recommended volumetric mixing ratio of UCO biodiesel should be no larger than 20%. The present study could be helpful for the investigation of UCO biodiesel blends as a potential fuel to satisfy the energy demand.
废食用油(UCO)生物柴油可能是中国最具潜力的替代燃料之一,可降低交通运输对原油的依赖。通过将弹性体材料浸入传统化石柴油、体积混合比为5%、10%和20%的UCO生物柴油与纯UCO生物柴油中,开展了一项实验研究,以评估上海生产的UCO生物柴油与弹性体材料在高速船用柴油发动机上的相互作用。试验持续时间为168小时,温度分别为25℃、50℃和70℃。同时,分析了UCO生物柴油混合比和浸泡温度对弹性体材料与UCO生物柴油相容性的影响。结果表明,与暴露于石油柴油中的情况相比,丁腈橡胶(NBR)、三元乙丙橡胶(EPDM)、氟橡胶(FKM)和硅橡胶(SR)等弹性体材料暴露于生物柴油混合物中时,质量和体积略有增加,拉伸强度和硬度下降,变化虽更差但仍可接受。FKM、NBR和SR与纯UCO生物柴油的相容性优于柴油,随着混合比的增加,EPDM与UCO生物柴油的相容性变差。总体而言,UCO生物柴油的推荐体积混合比应不大于20%。本研究有助于调查UCO生物柴油混合物作为满足能源需求的潜在燃料的情况。