Unidad de Investigación en Nutrición, Salud, Alimentos Funcionales y Nutraceúticos, Universidad San Ignacio de Loyola (UNUSAN-USIL), Calle Toulon 310, 15024 Lima, Peru; Facultad de Ciencias de la Salud, Universidad San Ignacio de Loyola, Av. La Fontana 750, 15024 Lima, Peru; Department of Analytical Chemistry, University of Seville, c/ Prof. García González 2, 41012 Seville, Spain.
Department of Analytical Chemistry, University of Seville, c/ Prof. García González 2, 41012 Seville, Spain.
Food Res Int. 2021 Feb;140:110022. doi: 10.1016/j.foodres.2020.110022. Epub 2020 Dec 17.
Sacha inchi is a super seed primarily grown in the Amazon rainforest of Peru. One of the main products obtained from seeds is oil. This product is rich in polyunsaturated fatty acids, tocopherols, and sterols. The objective of this work was to authenticity evaluate of the Sacha inchi oil by means of characterization of phenols, volatile compounds, and sensory profile. The phenolic and volatile compounds were analyzed using liquid chromatography-electrospray ionization-time of flight/mass spectrometry (HPLC-ESI-TOF/MS) and headspace solid phase microextraction combined with gas chromatography and mass spectrometry (HS-SPME/GC-MS), respectively. A total of 16 phenolic compounds were detected in commercial Sacha inchi oils, while 54 compounds have been found in the volatile fraction. These compounds mainly correspond to notes generated by alcohols, aldehydes, acids, ketones, and terpenoids. Principal component analysis (PCA) showed that the first two PCs account for 71.13% of total variance. Statistical analysis was used to observe the relationships between phenolic and volatile compounds; therefore, consequently, it has been found that 16 volatile compounds may have a significant influence upon overall perceived flavor and odor of the commercial Sacha inchi oils. According to the odor and flavor, the Sacha inchi oil is characterized by "green" odor notes, seed, dried fruit and rough.
奇亚籽油是一种主要生长在秘鲁亚马逊雨林中的超级种子。从种子中提取的主要产品之一是油。这种产品富含多不饱和脂肪酸、生育酚和甾醇。本工作的目的是通过对酚类物质、挥发性化合物和感官特性的分析,对奇亚籽油进行真实性评估。采用液相色谱-电喷雾电离-飞行时间/质谱联用(HPLC-ESI-TOF/MS)和顶空固相微萃取结合气相色谱-质谱联用(HS-SPME/GC-MS)分别对酚类化合物和挥发性化合物进行了分析。在商业奇亚籽油中检测到 16 种酚类化合物,而在挥发性成分中发现了 54 种化合物。这些化合物主要对应于醇、醛、酸、酮和萜烯类化合物产生的香气。主成分分析(PCA)表明,前两个主成分占总方差的 71.13%。统计分析用于观察酚类化合物和挥发性化合物之间的关系;因此,发现 16 种挥发性化合物可能对商业奇亚籽油的整体感知风味和气味有显著影响。根据气味和风味,奇亚籽油的特点是“绿色”气味、种子、干果和粗糙。