Wehner Linda A, Mittal Neeru, Liu Tian, Niederberger Markus
Laboratory for Multifunctional Materials, Department of Materials, ETH Zurich, Vladimir-Prelog-Weg 5, 8093 Zurich, Switzerland.
ACS Cent Sci. 2021 Feb 24;7(2):231-244. doi: 10.1021/acscentsci.0c01318. Epub 2021 Jan 26.
The primary task of a battery is to store energy and to power electronic devices. This has hardly changed over the years despite all the progress made in improving their electrochemical performance. In comparison to batteries, electronic devices are continuously equipped with new functions, and they also change their physical appearance, becoming flexible, rollable, stretchable, or maybe transparent or even transient or degradable. Mechanical flexibility makes them attractive for wearable electronics or for electronic paper; transparency is desired for transparent screens or smart windows, and degradability or transient properties have the potential to reduce electronic waste. For fully integrated and self-sufficient systems, these devices have to be powered by batteries with similar physical characteristics. To make the currently used rigid and heavy batteries flexible, transparent, and degradable, the whole battery architecture including active materials, current collectors, electrolyte/separator, and packaging has to be redesigned. This requires a fundamental paradigm change in battery research, moving away from exclusively addressing the electrochemical aspects toward an interdisciplinary approach involving chemists, materials scientists, and engineers. This Outlook provides an overview of the different activities in the field of flexible, transient, and transparent batteries with a focus on the challenges that have to be faced toward the development of such multifunctional energy storage devices.
电池的主要任务是存储能量并为电子设备供电。尽管在改善其电化学性能方面取得了诸多进展,但多年来这一任务几乎没有改变。与电池相比,电子设备不断配备新功能,其外观也在变化,变得可弯曲、可卷曲、可拉伸,甚至可能是透明的,或者是瞬态的或可降解的。机械柔韧性使其适用于可穿戴电子产品或电子纸;透明屏幕或智能窗户需要具备透明性,而可降解性或瞬态特性则有可能减少电子垃圾。对于完全集成且自给自足的系统,这些设备必须由具有相似物理特性的电池供电。为了使目前使用的刚性且笨重的电池具备柔韧性、透明性和可降解性,整个电池架构,包括活性材料、集流体、电解质/隔膜和封装,都必须重新设计。这需要电池研究领域进行根本性的范式转变,从仅关注电化学方面转向涉及化学家、材料科学家和工程师的跨学科方法。本展望概述了柔性、瞬态和透明电池领域的不同活动,重点关注开发此类多功能储能设备所面临的挑战。