由三联苯膦支持的第10族金属的零价ML配合物。
Zero-valent ML complexes of group 10 metals supported by terphenyl phosphanes.
作者信息
Martín M Trinidad, Marín Mario, Rama Raquel J, Álvarez Eleuterio, Maya Celia, Molina Francisco, Nicasio M Carmen
机构信息
Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, Sevilla 41071, Spain.
出版信息
Chem Commun (Camb). 2021 Mar 28;57(25):3083-3086. doi: 10.1039/d1cc00676b. Epub 2021 Mar 3.
PMID:33656041
Abstract
Bulky terphenyl phosphane ligands PMeAr' (Ar' = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in the solid state due to the existence of Ni-C interactions with the terphenyl fragment.
摘要
庞大的三联苯膦配体PMeAr'（Ar' = 三联苯基）有助于分离镍、钯和铂的零价双膦配合物。由于与三联苯片段存在Ni-C相互作用，前者在固态下显示出大于二的配位数。
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